FIELD: chemistry.
SUBSTANCE: invention relates to electrochemical method of obtaining copper acetylenides. Acetylenides of general formula R-C≡C-Cu, where R-alkyl (C6-C8), aryl is obtained by electrolysis of solution, which consists of alkyne of general formula R-C≡CH, where R-alkyl (C6-C8), aryl, anhydrous salt of alkaline-earth metal of general formula MX2, where M=Mg, Ca; X=Cl, Br, I and bipolar aprotic solvent (N,N-dimethylformamide, H,N-dimethylacetamide) in molar ratio alkyne : MX2 : solvent - 1:3:15 on copper electrodes and controlled potential E=2.4 V.
EFFECT: application of claimed method makes it possible to exclude toxic and expensive reagents, extend base of raw material, and simplify technology.
1 ex
| Title | Year | Author | Number |
|---|---|---|---|
| METHOD OF OBTAINING COMPLEX SOLUTIONS OF COPPER ACETYLENIDES | 2014 |
|
RU2558137C1 |
| METHOD OF PREPARING COMPLEX SOLUTIONS OF COPPER ACETYLENIDES | 2010 |
|
RU2429239C1 |
| METHOD FOR SEPARATION OF COPPER ACETYLENIDES FROM THEIR MIXTURE | 2021 |
|
RU2785533C1 |
| METHOD FOR PRODUCING COMPLEX SOLUTIONS OF COPPER ACETYLENIDES | 2016 |
|
RU2626653C1 |
| METHOD FOR PREPARING COMPLEX COMPOUNDS OF COPPER ACETYLENIDES WITH ALKALINE EARTH METAL HALIDES | 2023 |
|
RU2810262C1 |
| METHOD FOR PRODUCING COMPLEX SOLUTIONS OF COPPER ACETYLENIDES USING ZIRCONIUM SALT | 2016 |
|
RU2626652C1 |
| METHOD OF PRODUCING IODINE-ACETYLENE COMPOUNDS | 0 |
|
SU1712350A1 |
| METHOD FOR PRODUCTION OF INTERCALATION COMPOUNDS ON THE BASE OF LAMELLATED METAL DICHALCOGENIDES AND TETRAALKYL AMMONIUM CATIONS | 2010 |
|
RU2441844C1 |
| METHOD OF OBTAINING ALKYNYLSILANES | 2008 |
|
RU2368615C1 |
| METHOD OF SYNTHESIS OF ASYMMETRICALLY SUBSTITUTED TRIAZINES | 1994 |
|
RU2125995C1 |
