FIELD: chemistry.
SUBSTANCE: invention relates to the chemistry of complex compounds of zirconium salts with organic compounds, namely to a method for producing complex solutions of copper acetylides of formula RC≡C-Cu⋅3Z, where R is alkyl, aryl, Z - ZrOCl2⋅8H2O, in a bipolar aprotic solvent (N,N-dimethylformamide, N,N-dimethylacetamide) under normal conditions for 25-30 minutes. Herewith the solution is produced from copper acetylide of general formula R-C≡C-Cu and tetrahydroborate Z at a molar ratio of copper acetylides: Z=1:3. The produced solutions of copper acetylides can be used as catalysts or starting compounds for the preparation of catalysts, and also as reagents for the dissolution of copper acetylides.
EFFECT: increasing the yield.
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Authors
Dates
2017-07-31—Published
2016-07-25—Filed