FIELD: chemistry.
SUBSTANCE: said composition is a reaction product of the following three components: A) a titanium halide, B) an organoaluminium compound, primarily consisting of alkyl aluminium of general formula AlR3, and C) an electron donor consisting of a polyether of general formula R0O(R1O)pR2 (I) and/or a tetrahydrofurfuryl ether of general formula
(II).
Values of radicals R0, R1, R2 and R3 are given in the claim. The molar ratio of component B to component A is in the range of 0.01-10:1 and the molar ratio of component C to component B is in the range of 0.001-10:1. The invention also relates to a method of producing said heterogeneous catalyst composition and to a method of polymerising isoprene using said composition.
EFFECT: obtaining a catalyst for polymerisation of isoprene with high activity and improved properties of the obtained polymer.
16 cl, 2 ex
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Authors
Dates
2015-11-27—Published
2011-10-03—Filed