FIELD: chemistry.
SUBSTANCE: invention relates to method of alkylation of isoparaffins. Method includes passing isoparaffin, containing from 4 to 10 carbon atoms, into alkylation reactor; and passing olefin, containing from 2 to 10 carbon atoms, into alkylation reactor, where alkylation reactor functions under conditions of carrying out reaction and contains catalyst in form of phosphonium-based ionic liquid to carry out reaction between olefin and isoparaffin with obtaining alkylate, where phosphonium-based ionic liquid represents quaternary phosphonium halogenaluminate, which contains phosphonium-based organic cation and inorganic anion and possesses structure in form PhR1R2R3R4, where R1, R2 and R3 include identical alkyl groups, containing from 3 to 6 carbon atoms, and alkyl group R4 contains at least 1 carbon atom more than alkyl group R1 and has from 4 to 12 carbon atoms.
EFFECT: application of claimed method makes it possible to carry out reaction at the environment temperature or close to it.
9 cl, 4 dwg, 4 tbl, 30 ex
Title | Year | Author | Number |
---|---|---|---|
ALKYLATION PROCESS USING PHOSPHONIUM BASED IONIC LIQUIDS AS CATALYSTS | 2013 |
|
RU2620085C2 |
TRIALKYLPHOSPHONIUM IONIC FLUIDS, METHODS FOR OBTAINING AND METHODS FOR ALKYLATION WITH USE OF TRIALKYLPHOSPHONIUM IONIC FLUIDS | 2017 |
|
RU2675845C1 |
IONIC LIQUID | 2014 |
|
RU2654697C2 |
REACTION ZONE OF HF-ALKYLATION MODIFIED FOR ALKYLATION WITH IONIC LIQUID | 2016 |
|
RU2696281C2 |
METHOD FOR ALKYLATION CATALYZED WITH LIQUID ACID | 2019 |
|
RU2782562C2 |
REDUCTION OF THE CATALYST IN THE FORM OF AN IONIC LIQUID WITH A REDUCED QUANTITY OF HYDROGEN | 2019 |
|
RU2759857C1 |
REDUCTION OF CATALYST IN THE FORM OF IONIC LIQUID | 2019 |
|
RU2759569C1 |
0 |
|
SU316245A1 | |
CATALYTIC COMPOSITION AND METHOD FOR LIQUID-PHASE OLEFIN ALKYLATION | 1993 |
|
RU2104087C1 |
METHOD FOR PREPARING ALKYLENE GLYCOLS | 1999 |
|
RU2222522C2 |
Authors
Dates
2015-12-10—Published
2013-06-20—Filed