FIELD: chemistry.
SUBSTANCE: catalytic composition includes the following components, wt %: aluminium oxide - 2.0-77.0; oxide and/or sulphate of alkali-earth metal - 1.0-6.0; sulphate ion - 2.0-9.0; titanium dioxide - the remaining part. As oxide component, titanium catalytic composition includes modified sulphated titanium dioxide, which is obtained by mixing, at least, one oxide and/or sulphate of alkali-earth metal with hydrated sulphated titanium dioxide with the following hydrothermal processing at temperature 50-120°C and drying. Method for obtaining catalytic composition includes said modified titanium compound, where further obtained modified sulphated titanium dioxide is dried, subjected to mechanical-chemical activation and mixed with hydroxide compounds of aluminium or modified sulphated titanium dioxide is mixed with aluminium hydroxide compounds with carrying out combined mechanical-chemical activation. Pore-forming additives and binding agent are added to obtained product, moulding, drying and thermal processing at temperature 300-700°C are carried out. Claimed composition makes it possible to obtain catalysts for heterogenic reactions, which have different composition, which can be formed depending on application and exploitation conditions.
EFFECT: development of catalytic composition based on aluminium oxides and titanium dioxide with different ratio of aluminium oxide and titanium dioxide with increased mechanical strength, thermal and hydrothermal stability and environmentally friendly method for its obtaining.
20 cl, 7 tbl, 15 ex
Title | Year | Author | Number |
---|---|---|---|
CATALYTIC COMPOSITION BASED ON TITANIUM AND ALUMINUM OXIDE COMPOUNDS AND ITS APPLICATION | 2021 |
|
RU2775472C1 |
METHOD FOR PREPARATION OF MOLDED VANADIUM-TITANIUM CATALYST FOR CLEANING GASES | 1990 |
|
RU2050194C1 |
CATALYST FOR REMOVING SULFUR COMPOUNDS FROM INDUSTRIAL GASES AND A METHOD FOR PREPARATION THEREOF | 2005 |
|
RU2280505C1 |
CATALYST FOR PRODUCTION OF SULFUR BY CLAUS PROCESS AND METHOD OF ITS PRODUCTION | 2000 |
|
RU2176156C2 |
CATALYST FOR SYNTHESIS OF FORMIC ACID AND METHOD FOR PRODUCTION THEREOF (VARIANTS) | 2020 |
|
RU2747561C1 |
CATALYST FOR TREATING GASES CONTAINING SULFUR COMPOUNDS AND GAS TREATMENT METHOD | 1995 |
|
RU2112595C1 |
METHOD OF PRODUCING ALUMINA CATALYSTS OF THE CLAUS PROCESS AND USE THEREOF ON SULFUR PRODUCTION PLANTS | 2019 |
|
RU2711605C1 |
METHOD FOR PROCESSING INDUSTRIAL GASES | 1987 |
|
RU2009104C1 |
CATALYST TO PURIFY DISCHARGING INDUSTRIAL GASSES BY CLAUS REACTION | 1991 |
|
SU1822529A3 |
CATALYST AND METHOD FOR TREATING GASES CONTAINING SULFUR COMPOUNDS | 1995 |
|
RU2103058C1 |
Authors
Dates
2016-02-10—Published
2015-01-27—Filed