METHODS TO STORE TRANSITION METAL ORGANOPHOSPHOROUS LIGAND BASED CATALYSTS Russian patent published in 2016 - IPC B01J31/18 B01J31/40 C07C45/80 C07C45/50 

Abstract RU 2598386 C2

FIELD: chemistry.

SUBSTANCE: present invention relates to methods of producing a hydroformylation catalyst solution for storage, wherein catalyst solution contains: A. a transition metal in combination with one or more organophosphorus ligands, (B). a certain concentration of acid particles and C. water. First version of method includes a step for reducing concentration of acid particles in catalyst solution to not more than 200 ppm. Second version of method includes a step of mixing catalyst solution with aqueous buffer solution, containing one or more materials, which will neutralise and/or absorb, at least 50 % of acid particles.

EFFECT: proposed versions of method enable to reduce degradation of organophosphorus ligands during temporary suspension of hydroformylation process.

21 cl

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RU 2 598 386 C2

Authors

Ajzenshmid Tomas K.

Bekker Mikhael K.

Kempbell Donald L.

Bremmer Majkl A.

Miller Glenn A.

Lord Edrian

Rudolf Jens

Re Khans-Ryudiger

Dates

2016-09-27Published

2012-04-13Filed