FIELD: chemistry.
SUBSTANCE: present invention relates to methods of producing a hydroformylation catalyst solution for storage, wherein catalyst solution contains: A. a transition metal in combination with one or more organophosphorus ligands, (B). a certain concentration of acid particles and C. water. First version of method includes a step for reducing concentration of acid particles in catalyst solution to not more than 200 ppm. Second version of method includes a step of mixing catalyst solution with aqueous buffer solution, containing one or more materials, which will neutralise and/or absorb, at least 50 % of acid particles.
EFFECT: proposed versions of method enable to reduce degradation of organophosphorus ligands during temporary suspension of hydroformylation process.
21 cl
Title | Year | Author | Number |
---|---|---|---|
HYDROFORMYLATION METHOD | 2015 |
|
RU2674698C1 |
METHOD FOR STABILIZING PHOSPHITE LIGAND AGAINST DEGRADATION | 2013 |
|
RU2639156C2 |
METHOD FOR HYDROFORMYLATION WITH IMPROVED CONTROL OVER PRODUCT ISOMERS | 2008 |
|
RU2458906C2 |
HYDROFORMYLATION METHOD | 2015 |
|
RU2699368C2 |
METHODS FOR CONVERTING OLEFINS INTO ALCOHOLS, ESTERS, OR COMBINATIONS THEREOF | 2017 |
|
RU2751511C2 |
REGULATION OF RATIO ALDEHYDE OF NORMAL STRUCTURE: ALDEHYDE OF ISO-STRUCTURE IN PROCESS OF HYDROFORMYLATION WITH MIXED LIGAND BY REGULATION OF SYNTHESIS-GAS PARTIAL PRESSURE | 2010 |
|
RU2546110C2 |
METHOD OF HYDROFORMYLATION BY MEANS OF DOUBLE OPEN-END BISPHOSPHITE LIGAND | 2009 |
|
RU2541537C2 |
CATALYST PRODUCTION METHOD | 2013 |
|
RU2639874C2 |
METHOD FOR HYDROFORMYLATION | 2013 |
|
RU2634719C2 |
METHODS FOR PRODUCING ORGANOPHOSPHORUS COMPOUNDS | 2016 |
|
RU2733459C2 |
Authors
Dates
2016-09-27—Published
2012-04-13—Filed