FIELD: chemistry.
SUBSTANCE: process comprises reacting phenol or its derivatives with a ketone or aldehyde at a temperature of 30-80°C in presence of a catalyst and hydrogen sulfide promoter. The cation-exchange resin is used as the catalyst, and hydrogen sulfide is fed at a pressure of 0.1-1.0 MPa, at a molar ratio of ketone or aldehyde: phenol or its derivatives: hydrogen sulphide 1: (2-10):(0.12-0.7).
EFFECT: method allows to produce high-quality bisphenols with main substance content of not less than 99,9 percent in high yield.
3 cl, 1 tbl, 2 ex
Title | Year | Author | Number |
---|---|---|---|
METHOD OF SYNTHESIS OF BISPHENOL-A | 1994 |
|
RU2119906C1 |
METHOD OF OBTAINING BISPHENOL-A | 2019 |
|
RU2799337C2 |
METHOD OF PRODUCING ALKYL MERCAPTANS | 2023 |
|
RU2817954C1 |
MODIFIED ION EXCHANGE RESIN AND METHOD FOR OBTAINING BISPHENOLS | 2005 |
|
RU2337753C1 |
METHOD FOR PRODUCING CATALYST FOR MAKING ISOPROPYL ALCOHOL | 2022 |
|
RU2800947C1 |
CATALYST FOR ISOMERISATION OF PARAFFIN HYDROCARBONS AND PREPARATION METHOD THEREOF | 2015 |
|
RU2595341C1 |
METHOD OF PREPARING CATALYST AND METHOD OF PRODUCING ISOPROPYL ALCOHOL USING SAID CATALYST | 2020 |
|
RU2738656C1 |
PROCESSING OF RESIDUAL FLOWS FROM BISPHENOL PRODUCTION | 2018 |
|
RU2782457C2 |
METHOD FOR SELECTIVE PRODUCTION OF N-METHYL-PARA-PHENETIDINE | 2011 |
|
RU2471771C1 |
METHOD FOR SELECTIVE PRODUCTION OF N-METHYL-PARA-ANISIDINE | 2011 |
|
RU2472774C1 |
Authors
Dates
2017-07-21—Published
2016-06-15—Filed