FIELD: chemistry.
SUBSTANCE: invention relates to styrene-butadiene rubber based on solution with high content of styrene and vinyl units (SSBR) and to its production method. Method of polymerizing a polymer containing monomeric units obtained from a styrene monomer and a 1.3-butadiene monomer is disclosed. Polymerization of the monomeric units is carried out in the presence of an initiator, the first polar agent and the second polar agent. The first polar agent comprises the following structure (I): R1'R2'N-Q-NR3'R4'. The second polar agent comprises the following structure (II). The polymer has a glass transition temperature between -50°C and 20°C. The polymer obtained by the mentioned method is described as a composition comprising such polymer and an article comprising at least one component formed from such composition.
EFFECT: providing SSBR with high content of styrene and vinyl units with significantly narrowed range of the molecular mass distribution and increased activity of polymer chain at the end of polymerization.
18 cl, 4 dwg, 9 ex
Title |
Year |
Author |
Number |
STYRENE-BUTADIENE RUBBER WITH HIGH CONTENT OF STYRENE AND VINYL LINKS AND METHODS FOR PRODUCTION THEREOF |
2012 |
- Khamann Evemari
- Valenti Silviya
- Shmidel Karin
|
RU2606129C2 |
STYRENE-BUTADIENE RUBBER WITH HIGH CONTENT OF STYRENE AND VINYL UNITS AND NARROW DISTRIBUTION OF MOLECULAR WEIGHT AND METHOD OF ITS PREPARATION |
2012 |
- Khamann Evemari
- Valenti Silviya
- Kholtts Gabriele
|
RU2632867C2 |
HIGH STYRENE HIGH VINYL STYRENE-BUTADIENE RUBBER WITH NARROW MOLECULAR WEIGHT DISTRIBUTION AND METHODS FOR PREPARATION THEREOF |
2012 |
- Khamann Evemari
- Valenti Silviya
- Kholtts Gabriele
|
RU2608041C2 |
LOW-VINYL STYRENE-BUTADIENE POLYMERS AND METHODS FOR OBTAINING THEREOF |
2011 |
- Valenti Sil'Vija
- Khamann Ehvemari
|
RU2562458C2 |
STYROL-BUTADIENE RUBBER, CHARACTERISED BY NEW STYRENE INCLUSION |
2010 |
- Khamann Ehvemarie
- Bartossek Khagen Tomas
- Kizekamp Joakhim
|
RU2541476C2 |
MODIFIED POLYMER COMPOSITIONS |
2012 |
- Valenti Silviya
- Khamann Evemari
- Yanch Norbert
- Tile Sven
|
RU2599723C2 |
DILITHIUM INITIATOR FOR ANIONIC (CO)POLYMERIZATION, METHOD FOR PREPARING THE SAME, METHOD FOR PRODUCING DIENE RUBBERS BASED ON THE INITIATOR |
2014 |
- Budeeva Anna Viktorovna
- Shirin Kirill Nikolaevich
|
RU2667061C1 |
STYRENE-BUTADIENE POLYMERS WITH STYRENE GRADIENT AND METHODS FOR PRODUCTION THEREOF |
2009 |
- Khamann Ehvemarie
- Bartossek Khagen
|
RU2501816C2 |
POLAR MODIFIER SYSTEMS FOR BLOCK COPOLYMERISATION WITH HIGH CONTENT OF VINYL |
2017 |
- Elisarraras Maja Daniel Abraam
- Khardimen Kristofer Dzh.
- Korona Galvan Serkhio
- Moktesuma Espirikueto Serkhio Alberto
- Rodriges Gvadarrama Luis Antonio
|
RU2719600C1 |
MIXTURES OF AMINOSILYL-FUNCTIONALIZED STYRENE, THEIR PRODUCTION, AND THEIR USE IN PRODUCTION OF ELASTOMERIC COPOLYMERS |
2019 |
- Siolek, Maria
- Skrok, Tomasz
- Rogoza, Jaroslaw
- Kozak, Radoslaw
- Weda, Pawel
- Walenia, Malgorzata
|
RU2780620C2 |