FIELD: chemistry.
SUBSTANCE: method involves thermal decomposition of calcium hypochlorite with stirring with hot steam in the presence of a nichrome catalyst treated in a pickling tank with a solution of hydrochloric acid. In the spent hydrochloric acid solution formed during the processing of the nichrome catalyst after its use in the process of thermal decomposition of calcium hypochlorite, the content of active chlorine is determined. When the spent hydrochloric acid solution is stirred, a solution of sodium thiosulfate is gradually added. The amount of sodium thiosulfate solution in the spent hydrochloric acid solution is maintained at 5-15 times excess from the stoichiometrically necessary one. The neutralized solution is drained into sewage.
EFFECT: reducing toxic substances and active chlorine in wastewater.
5 cl, 1 ex
Title | Year | Author | Number |
---|---|---|---|
METHOD OF DECONTAMINATING CALCIUM HYPOCHLORITE PULP | 2018 |
|
RU2687455C1 |
TITANIUM-MAGNESIUM PRODUCTION OFF-GAS PURIFICATION | 2014 |
|
RU2571767C2 |
METHOD OF TREATING MAGNESIUM PRODUCTION EMISSION GASES TO REMOVE CHLORINE AND HYDROGEN CHLORIDE | 2003 |
|
RU2243024C1 |
METHOD OF DETOXICATION AND UTILIZATION OF HYPOCHLORITE SOLUTIONS | 1996 |
|
RU2091327C1 |
METHOD FOR DEHYDRATION OF PULP OF CALCIUM HYPOCHLORITE | 1994 |
|
RU2073637C1 |
METHOD OF PRODUCTION OF MAGNESIUM AND CHLORINE BY ELECTROLYSIS OF ANHYDROUS CHLORIDES | 2001 |
|
RU2209258C1 |
METHOD OF CLEANING MAGNESIUM PRODUCTION EMISSION GASES | 1999 |
|
RU2169037C1 |
METHOD FOR DEHYDRATING PUMP OF CALCIUM HYPOCHLORITE | 0 |
|
SU998326A1 |
PROCEDURE FOR PROCESSING WASTE OF MAGNESIUM PRODUCTION AND INSTALLATION FOR IMPLEMENTATION OF THIS PROCEDURE | 2009 |
|
RU2400292C1 |
METHOD OF INTEGRATED PROCESSING OF POLYMETALLIC PRODUCTION WASTES AND RENDERING THEM HARMLESS | 2001 |
|
RU2194782C1 |
Authors
Dates
2017-11-20—Published
2016-10-10—Filed