FIELD: chemistry.
SUBSTANCE: invention refers to the chemistry of coordination compounds, in particular to the method of producing chelate CIS-S,S-complexes of diacetate(dibromide)[di-1,6-(3,5-dimethylizoxazole-4-yl)-2.5-ditiahexane]palladium(II) of the common formula
(1) X=X'=CH3COO, Br. The method includes the interaction of the bidentate reagent of 1,2-bis[sulfanilate(3,5-dimethylisoxazole-4-yl)]ethane with diacetate (dibromide) palladium(II) in the environment of acetonitrile in the molar ratio of bis[sulfanilate(3,5-dimethylisoxazole-4-yl)]ethane: diacetate (dibromide) palladium(II) equal to 1:1, at a temperature of 15-25°C and atmospheric pressure for 3-5 hours.
EFFECT: resulting compounds can find application as biologically active substances with an anticancer activity and catalysts of chemical reactions.
1 tbl, 6 ex
| Title | Year | Author | Number |
|---|---|---|---|
| METHOD OF PRODUCING CHELATE CIS-S,S-COMPLEXES OF DICHLORODI-1,6-(3,5-DIMETHYL ISOXAZOLE-4-YL)-2,5-DITIAHEXANE PALLADIUM (II) AND PLATINUM (II) | 2015 |
|
RU2596874C1 |
| WATER-SOLUBLE CIS-S, S-COMPLEX DIACETATE [DI-1,6- (3,5-DIMETHYLISOXAZOL-4-YL) -2,5-DITHIAHEXANE] PALLADIUM (II), HAVING INHIBITORY ACTIVITY ON THE ENZYME Α-AMYLASE | 2019 |
|
RU2709512C1 |
| HEPATOPROTECTIVE CHELATE CIS-S,S-COMPLEX OF DICHLORO-DI-1,6-(3,5-DIMETHYLISOXAZOLE-4-YL)-2,5-DITHIOHEXANE OF PALLADIUM (II) | 2015 |
|
RU2612131C1 |
| METHOD OF PRODUCING CHELATED S,S-DIMIODI (I) BIS [(3,5-DIMETHYLISOXAZOL-4-YL)METHYLSULFANYL]ETHANE DICHLORIDE COMPLEX | 2016 |
|
RU2653920C2 |
| CATALYST FOR PRODUCING 3-(3-PHENYLPROP-2-YN-1-YL)-1,3-OXAZOLIDINE | 2016 |
|
RU2653989C2 |
| METHOD FOR PREPARING N-COMPLEXES OF DICHLORODI-[(4-(BENZYLSULFANYL)METHYL)-3,5-DIMETHYL-1H-PYRAZOLE]PALLADIUM (II) AND PLATINUM (II) | 2017 |
|
RU2672265C2 |
| N,N'-COMPLEX OF DIBROMODI-[(4-(BENZYLSULFANYL)METHYL-3,5-DIMETHYL-1N-PYRAZOLE]PALLADIUM(II) EXHIBITING ANTINEOPLASTIC ACTIVITY | 2018 |
|
RU2703536C1 |
| METHOD OF OBTAINING BIS-(1,5,3-DITHIAZEPINAN-3-YL)ETHANE AND ITS APPLICATION AS MEDICATION WITH ANTIFUNGAL ACTIVITY | 2013 |
|
RU2541791C2 |
| METHOD OF PRODUCING BIARYLS | 2009 |
|
RU2433112C2 |
| METHOD FOR PRODUCING N,N-COMPLEXES OF DICHLORODI-[3,5-DIMETHYL-4-(SULFANYLMETHYL)-1H-PYRAZOLE]COPPER DIHYDRATE (II) | 2017 |
|
RU2677484C2 |
