FIELD: lighting.
SUBSTANCE: lighting device 100 includes a light source 10 and a luminescent material 20 converting at least a portion of the emition 11 from the source 10 to emition 51. Source 10 includes a light emitting diode. Luminescent material 20 includes phosphor 40 having structure of UCr4C4, or an ordered version of UCr4C4 aristotype, or structure NaLi3SiO4 or structure KLi3GeO4 having the formula: M1-x-y-zZzAaBbCcDdEeN4-nOn: ESx, REy (I), in which M is selected from the group consisting of Ca, Sr, and Ba; Z, is selected from the group consisting of Na, K and Rb; A is selected from the group consisting of Mg, Zn and Cd; B is selected from the group consisting of B, Al and Ga; C is selected from the group consisting of tetravalent Si, Ge, Ti, and Hf; D is selected from the group consisting of monovalent Li and Cu; E, is selected from the group consisting of P, V, Nb and Ta; ES is selected from the group consisting of divalent Eu, Sm and Yb; RE, is selected from the group consisting of trivalent Ge, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er and Tm; 0≤x≤0.2; 0≤y≤0.2; 0≤x+y≤0.4; 0≤z<1; 0≤n≤0.5; 0≤a≤4; 0≤b≤4; 0≤c≤4; 0≤d≤4; e=0; a+b+c+d+e=4; 2a+3b+4c+d+5e=10-y-n+z. Phosphor particles may have a coating of the group consisting of AlPO4-coating, Al2O3-coating or SiO2-coating. The luminescent material 20 may further include phosphores selected from Ba0.95Sr0.05Mg2Ga2N4:Eu, BaMg2Ga2N4:Eu, SrMg3SiN4:Eu, SrMg2Al2N4:Eu, SrMg2Ga2N4:Eu, BaMg3SiN4:Eu, CaLiAl3N4:Eu, SrLiAl3N4:Eu, CaLi0.5MgAl2.5N4:Eu and SrLi0.5MgAl2.5N4:Eu.
EFFECT: coefficient of efficiency and light output of lighting device are increased.
17 cl, 13 dwg, 4 tbl
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Authors
Dates
2018-01-16—Published
2013-05-09—Filed