FIELD: chemistry.
SUBSTANCE: fluosilicates are treated with sodium hydroxide and/or sodium carbonate at a temperature of 80-100°C. The resulting sodium fluoride and sodium silicate solution are separated by filtration. Sodium fluoride is either isolated or treated with concentrated sulfuric acid at a temperature of 130-150°C and hydrogen fluoride is separated off, which is absorbed by water to form hydrofluoric acid. The residue obtained after extraction of hydrogen fluoride is treated with a hydroxide and/or sodium carbonate to form sodium sulfate. A solution of sodium silicate is subjected to carbon dioxide treatment and silica is recovered.
EFFECT: disposal of production wastes generated during the production of phosphorus fertilizers and processing of aluminium ores is ensured, with the production of pure products from them.
6 tbl, 10 ex
Title | Year | Author | Number |
---|---|---|---|
METHOD OF PRODUCING SODIUM SILICOFLUORIDE | 2012 |
|
RU2492142C1 |
METHOD FOR PRODUCTION OF HIGH-PURITY POLYCRYSTALLINE SILICON | 1993 |
|
RU2078034C1 |
METHOD FOR SYNTHESIS OF SODIUM SILICOFLUORIDE | 2009 |
|
RU2411183C1 |
METHOD OF PRODUCING SILICON TETRAFLUORIDE | 2001 |
|
RU2182558C1 |
METHOD OF SILICON TRIFLUORIDE PRODUCING | 1991 |
|
RU2046095C1 |
METHOD FOR SYNTHESIS OF INORGANIC FLUORINE-CONTAINING COMPOUNDS | 2004 |
|
RU2278073C1 |
METHOD OF OBTAINING HIGHLY DISPERSED SILICON DIOXIDE | 2013 |
|
RU2564361C2 |
COMPLEX PROCESSING OF COAL COMBUSTION FLUE ASH | 2012 |
|
RU2502568C2 |
METHOD FOR HYDROCHEMICAL PREPARING HIGHLY DISPERSED SILICON DIOXIDE FROM TECHNOGENIC SILICON-CONTAINING RAW | 2004 |
|
RU2261841C1 |
METHOD OF SILICON REDUCTION | 2007 |
|
RU2358906C2 |
Authors
Dates
2018-01-22—Published
2016-02-11—Filed