FIELD: chemistry.
SUBSTANCE: invention relates to methods for joint hydroblasting of fatty acid triglycerides and straight-run diesel fraction on sulfide catalysts in order to obtain low-sulfur hydrocarbon fractions and it can be used in the petroleum industry. Resulting hydrocarbon fractions can be directly used as diesel fuel, or can be further processed, if necessary, during the isomerization process in order to improve the low temperature properties. Method for hydrotreating triglycerides of fatty acids (TLC) in a mixture with petroleum fractions at an elevated temperature and pressure of hydrogen on sulfide catalysts MoS2/Al2O3 and NiMo/Al2O3 in two stages is proposed, where in the first stage hydrotreating the straight-run diesel fraction in the presence of sulphide NiMo/Al2O3 catalyst, then the obtained mixture of hydrocarbons, hydrogen and hydrogen sulfide is mixed with fatty acid triglycerides and a hydrodeoxygenation reaction is carried out in the presence of a sulfide catalyst MoS2/Al2O3.
EFFECT: high efficiency of the process of joint hydrotreating of diesel fractions and triglycerides of fatty acids.
1 cl, 1 tbl, 4 ex
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Authors
Dates
2018-05-04—Published
2017-12-28—Filed