FIELD: biochemistry.
SUBSTANCE: invention relates to basic organic and petrochemical synthesis and can be used for producing 4,4-dimethyl-1,3-dioxane by condensation of isobutylene and formaldehyde. Proposed are synthetic zeolites of general formula Na12[(AlO2)12(SiO2)12]xH2O grade NaA with pore diameter 4 Å or Ca4,5Na3[(AlO2)12(SiO2)12]xH2O grade CaA with pore diameter 5 Å as heterogeneous cocatalysts. Synthesis of DMD is carried out in the presence of phosphoric acid, taken as the basic acid catalyst.
EFFECT: technical result is the increased selectivity in the production of 4,4-dimethyl-1,3-dioxane.
3 cl, 3 ex, 1 tbl
Title | Year | Author | Number |
---|---|---|---|
METHOD OF PRODUCING 4,4-DIMETHYL-1,3-DIOXANE (VERSIONS) | 2016 |
|
RU2631429C1 |
METHOD FOR OBTAINING 4,4-DIMETHYL-1,3-DIOXANE (VARIANTS) | 2021 |
|
RU2764520C1 |
APPLICATION OF CARBON NANOTUBES TO INCREASE SELECTIVITY IN PRODUCTION OF 4,4-DIMETHYL-1,3-DIOXANE | 2016 |
|
RU2658839C2 |
USE OF CARBON NANOTUBES TO INCREASE SELECTIVITY IN THE PRODUCTION OF 4,4-DIMETHYL-1,3-DIOXANE | 2021 |
|
RU2764519C1 |
APPLICATION OF POROUS POLYPHENYLENEPHTHALIDE TO INCREASE SELECTIVITY IN PRODUCTION OF 4,4-DIMETHYL-1,3-DIOXANE | 2018 |
|
RU2663294C1 |
USE OF POROUS POLYARYLENEPHTHALIDE TO INCREASE SELECTIVITY WHEN PRODUCING 4,4-DIMETHYL-1,3-DIOXANE | 2021 |
|
RU2768818C1 |
METHOD FOR PRODUCING 4,4-DIMETHYL-1,3-DIOXANE USING CARBON NANOTUBES | 2021 |
|
RU2764517C1 |
METHOD FOR PRODUCING 4,4-DIMETHYL-1,3-DIOXANE USING POLYARYLENE PHTHALIDE | 2021 |
|
RU2764518C1 |
METHOD OF PRODUCING 4,4-DIMETHYL-1,3-DIOXANE | 2023 |
|
RU2811258C1 |
METHOD OF PRODUCING 4,4-DIMETHYL-1,3-DIOXANE | 2016 |
|
RU2624678C1 |
Authors
Dates
2018-09-28—Published
2016-09-12—Filed