FIELD: chemistry.
SUBSTANCE: invention relates to methods for cleaving silicon-silicon bonds and / or chlorine-silicon bonds in monosilanes, polysilanes and / or oligosilanes. Method of cleaving silicon-silicon and / or chlorine-silicon bonds, wherein monosilane, polysilane and / or oligosilane is dissolved or suspended in ether or a hydrochloric acid solution in ether.
EFFECT: technical result is the disclosed method is technologically and economically advantageous for the preparation of halogenated oligosilanes from halogenated polysilanes and for producing siloxanes of organochlorosilanes and chlorinated monosilanes.
16 cl, 6 dwg, 7 tbl
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