FIELD: chemistry.
SUBSTANCE: invention relates to a method for combined production of 2,7-dialkyl-4,9 (10)-2,3a,5a,7,8a,10a-hexaazaperhydropyrenes of general formula (1), in which R is n-propyl, n-butyl, consisting in reaction of N,N-bis(methoxymethyl)-N-alkyl with isomer mixture of 2,6(7)-dimethyl-1,4,5,8-tetraazadecalin in medium of CH3OH-H2O in presence of SmCl3⋅6H2O catalyst in molar ratio of N,N-bis(methoxymethyl)-N-alkylamine : isomer mixture of 2,6(7)-dimethyl-1,4,5,8-tetraazadecalines : SmCl3⋅6H2O = 2:1:(0.03–0.07) at room temperature (~20 °C) temperature and atmospheric pressure for 2.5–3.5 hours. 
(1).
EFFECT: technical result is obtaining novel 2,7-dialkyl-4,9(10)-2,3a,5a,7,8a,10a-hexaazaperhydropyren of general formula (1) with high output.
1 cl, 1 tbl, 3 ex
| Title | Year | Author | Number |
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| METHOD OF OBTAINING 2,6-DIALKYL-HEXAHYDRO-1H,5H-2,3A,4A,6,7A,8A-HEXAAZACYCLOPENTA [def]FLUORENE-4,8-DIONS | 2014 |
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