FIELD: chemistry.
SUBSTANCE: invention relates to a method of producing 2,8-bis-cycloalkyl-2,3,8,9,12c,12d-hexahydro-1H,7H-5,11-dioxa-2,3a,4,6,6b,8,9a,10,12,12b-deacylacyclopent[e,l]pyrenes of general formula (1), in which 1,3,5-tricycloalkyl-1,3,5-triazinanes are reacted with 4a,5,9a,10-tetrahydro-4H,9H-[1,2,5]oxadiazolo[3,4-b][1,2,5]oxadiazolo[3’,4’:5,6]pyrazino[2,3-e]pyrazine in the medium of CH3OH-DMSO in presence of a NiCl2 catalyst in molar ratio of 1,3,5-tricycloalkyl-1,3,5-triazinane:4a,5,9a,10-tetrahydro-4H,9H-[1,2,5]oxadiazolo[3,4-b][1,2,5]oxadiazolo[3’,4’:5,6]pyrazino[2,3-e]pyrazine:NiCl2 = 2:1:(0.03–0.07) at room temperature (~20 °C) temperature and atmospheric pressure for 2.5–3.5 hours.
EFFECT: technical result is obtaining novel compounds of formula (1), which can be used as candidate compounds for developing drug preparations, luminescent intercalators and a base for designing so-called molecular devices, as well as promising components of explosives and rocket fuels.
1 cl, 1 tbl, 3 ex
Title |
Year |
Author |
Number |
2,8-BIS-(5-METHYLISOXAZOL-3-YL OR 1,5-DIMETHYL-3-OXO-2-PHENYL-1,2-DIHYDRO-3H-PYRAZOL-4-YL)-2,3,8, 9,12c,12d-HEXAHYDRO-1H,7H-5,11-DIOXA-2,3a.4,6,6b8,9a,10,12,12b-DECAAZADICYCLOPENTA[e,l]PYRENES, METHOD FOR THEIR PRODUCTION AND APPLICATION IN AS A PRODUCT WITH CYTOTOXIC ACTIVITY |
2021 |
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- Kirsanov Viktor Yurevich
- Dzhemileva Lilya Useinovna
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|
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