FIELD: chemistry.
SUBSTANCE: invention relates to a method of producing 2,7-dicycloalkyl-4,9-dimethyl-2,3a,5a,7,8a,10a-hexaazaperhydropyrenes of general formula (1), in which R is cyclo-C3H5, cyclo-C5H9, cyclo-C6H11, cyclo-C7H13, cyclo-C8H15, norbornyl-, consisting in reaction of 1,3,5-tricycloalkyl-1,3,5-triazine with 2,6-dimethyl-1,4,5,8-tetraazadecalin in medium of CH3OH-H2O in presence of NiCl2⋅6H2O catalyst in molar ratio of 1,3,5-tricycloalkyl-1,3,5-triazine : 2,6-dimethyl-1,4,5,8-tetraazadecalin : NiCl2⋅6H2O = 2:1:(0.03–0.07) at room temperature (~20 °C) temperature and atmospheric pressure for 2.5–3.5 hours 
1.
EFFECT: technical result: obtaining novel 2,7-dicycloalkyl-4,9-dimethyl-2,3a,5a,7,8a,10a-hexaazaperhydropyren of general formula (1) with high output.
1 cl, 1 tbl, 3 ex
| Title |
Year |
Author |
Number |
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2016 |
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