FIELD: organic chemistry.
SUBSTANCE: the invention relates to organic chemistry, namely to a method for producing (3bR*,7aR*,10bR*,14aR*-cis-14c,14d)-2,9-bis(methylphenyl or methoxyphenyl)octadecahydro-1H,8H-2,3a,7b,9,10a,14b-hexaazadibenzo[fg,op]tetracenes of the general formula (1). The method is carried out by the interaction of trans-1,6,7,12-tetraazaperhydrotetracene with formaldehyde and aniline derivatives of the formula Ar-NH2 in the presence of a catalyst Sm(NO3)3⋅6H2O at a molar ratio of trans-1,6,7,12-tetraazaperhydrotetracene : formaldehyde : aniline derivative : Sm(NO3)3⋅6H2O = 1 : 4 : 2 : (0.03-0.07) in a CH3OH medium at room temperature and atmospheric pressure for 2.5-3.5 hours.
EFFECT: method for obtaining compounds of formula (1).
$$$
1 cl, 1 tbl, 1 ex
Где - where
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