FIELD: technological processes.
SUBSTANCE: invention relates to a multimodal isoolefin copolymer composition for forming a molded article. Polyisoolefin-based copolymer composition has a multimodal molecular weight distribution and a level of unsaturation of more than 4 mol%, which can be obtained by copolymerisation of 70–96 vol% isoolefin monomer and 4–30 vol% β-pinene or multiolefin monomer based on isoolefin monomer volume and β-pinene or multiolefin monomer in solution containing 0–30 vol% of an aliphatic hydrocarbon diluent based on the volume of the solution, and initiating system based on aluminum alkyl halide. Multimodal molecular weight distribution of the composition contains a first molecular weight fraction having a peak molecular weight (Mp) of less than about 300 kg/mol, and a second molecular weight fraction having peak molecular weight (Mp) of more than about 1,000 kg/mol or at least 3 times more than Mp first molecular weight fraction.
EFFECT: composition is capable of processing, while maintaining physical characteristics and stability of dimensions required for treatment before vulcanisation.
13 cl, 12 dwg, 9 tbl, 37 ex
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Authors
Dates
2019-06-07—Published
2015-04-28—Filed