FIELD: chemistry.
SUBSTANCE: invention relates to a method of producing polysulphide by low-salt method. Method of producing polysulphide involves a step of reacting bis(2-haloalkyl) formal with sodium polysulphide (i) or a combination of sodium and sulfur bisulphide (ii). Reaction is carried out in the presence of a prepolymer of formula (I) X-(R2-O)n-CH2-O-(R1-O)m-CH2-(O-R2)p-X (I), in which R1 and R2 can be identical or different, selected from alkane chains containing 2–10 carbon atoms, X is a halogen atom, n, m and p are integers which can be identical or different and have a value in range from 1 to 6. Reaction is carried out in the absence of a dihaloated alkane.
EFFECT: invention enables to obtain a polysulphide polymer with low salt content, characterized by good chemical resistance, good compatibility with plasticisers and polar surfaces.
11 cl, 8 tbl, 5 ex
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Authors
Dates
2019-06-27—Published
2015-12-16—Filed