ISOBUTANOL CONVERSION METHOD Russian patent published in 2022 - IPC C07C1/20 C07C1/24 C07C11/02 C07C11/04 C07C11/06 C07C11/08 C07C15/04 C07C15/06 C07C15/08 C10G3/00 

Abstract RU 2768153 C1

FIELD: chemistry.

SUBSTANCE: present invention relates to a method of converting isobutanol to obtain a mixture of C2-C4 olefins and BTX. Method involves contacting isobutanol in a reactor with a catalyst which contains microporous zeolite MFI. Catalyst used is a composite based on microporous zeolite and mesoporous silicon carbide — MFI/SiC, which is characterized by: porous structure — volume of micropores 0.15–0.18 cm3/g and mesopores 0.05–0.07 cm3/g, content of strong acid centers 368–380 mcmol/g, with total content of acid centers equal to 714–728 mcmol/g, and contact is carried out at temperature of 580–620 °C at weight rate of isobutanol supply of 2.5–2.9 h-1 and supply of nitrogen to the reactor.

EFFECT: disclosed method increases propylene output, as well as output of C2-C4 olefins, BTX fractions and total output of C2-C4 olefins and BTX.

1 cl, 1 dwg, 4 ex

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RU 2 768 153 C1

Authors

Dedov Aleksej Georgievich

Karavaev Aleksandr Aleksandrovich

Loktev Aleksej Sergeevich

Zemlyanskij Petr Vitalevich

Dates

2022-03-23Published

2021-06-09Filed