FIELD: chemical or physical processes.
SUBSTANCE: invention relates to methods for reductive cleavage of a C–S bond in aromatic compounds in process streams. Disclosed is a method for reducing sulfur in fuel or fuel feedstock, which contains at least one aromatic substrate containing a hydrogen sulphide bond, where method includes contacting fuel or fuel material with a chemical system containing at least one organosilane having at least one silicon-hydrogen bond, at least one strong base and optionally at least one molecular hydrogen donor compound, molecular hydrogen or both, at temperature from 75 to 450 °C to reduce at least part of carbon-sulfur bonds in organic substrate.
EFFECT: elimination of sulfur from raw material streams for improvement of ecology and prevention of poisoning of catalysts from precious metals in catalytic converters.
20 cl, 2 dwg, 4 tbl, 22 ex
Title | Year | Author | Number |
---|---|---|---|
TRANSITION-METAL FREE REDUCTIVE CLEAVAGE OF AROMATIC C-O, C-N, AND C-S BONDS BY ACTIVATED SILANES | 2013 |
|
RU2650112C2 |
METHOD FOR REDUCTION IN LIGNIN CONTENT IN RAW MATERIALS FOR BIOMASS | 2021 |
|
RU2783531C1 |
TRANSITION-METAL-FREE SILYLATION OF AROMATIC COMPOUNDS | 2013 |
|
RU2651570C2 |
BIOCOMPOSITE PLATE | 2011 |
|
RU2586699C2 |
METHOD OF PRODUCING COMPLEXES OF RUTHENIUM AND INTERMEDIATE COMPOUNDS THEREOF AND USE THEREOF IN METATHESIS OF OLEFINS | 2016 |
|
RU2735724C1 |
METHODS OF PRODUCING JET FUEL FROM NATURAL OIL AS FEEDSTOCK THROUGH METATHESIS REACTIONS | 2009 |
|
RU2522436C2 |
STILBENE DERIVATIVE AND ITS PRODUCTION METHOD | 2017 |
|
RU2776328C2 |
SYNTHESIS OF 1,3-BUTADIENE | 2015 |
|
RU2700413C2 |
RUTHENIUM COMPLEXES CONTAINING PARACYCLOPHANE AND CARBONYL LIGANDS AND THEIR USE AS CATALYSTS | 2012 |
|
RU2614415C2 |
PHOSPHONIC ACID ESTERS AND METHODS FOR SYNTHESIS THEREOF | 2011 |
|
RU2581045C2 |
Authors
Dates
2022-04-01—Published
2013-10-02—Filed