FIELD: chemistry.
SUBSTANCE: invention relates to luminophores with the general formula AВС(ВO3)2, where A, B, C are cations of alkaline, alkaline earth, and rear earth metals emitting light in the infrared region. Photoluminescent material of NaSrYb(BO3)2 composition emits light in the infrared region, in the range from 950 to 1050 nm, and has a P21/m spatial group of monoclinic syngony, lattice parameters a=9.0561(6) b=5.29230(5) с=6.4267(4) β=118.528(4)°. A method for the production of photoluminescent material of NaSrYb(BO3)2 composition by two-stage solid-phase synthesis includes preparation of a mixture of components taken in a stoichiometric ratio, containing, respectively, wt.%: sodium carbonate Na2CO3 – 10.04, strontium carbonate SrCO3 – 27.97, Yb2O3 – 37.33, and boric acid Н3ВO3 – 24.66. The mixture is heated, at the first stage, to 650°C for at least 5 h, ground to obtain homogenous mass, then heated, at the second stage, to 900°C for at least 12 h.
EFFECT: group of inventions provides for expansion of the arsenal of materials having photoluminescent properties.
2 cl, 4 dwg, 1 ex
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Authors
Dates
2022-12-19—Published
2021-10-27—Filed