FIELD: organic chemistry.
SUBSTANCE: invention relates to the field of organic chemistry, and in particular to a method for producing carboxyl-containing azoxybenzenes of the general formula
,
where X is OCH2 or CH=CH. The method consists in the reduction of nitroaryl-containing carboxylic acids of the general formula , where X=OCH2, 4-NO2; X=CH=CH, 4-NO2; X=CH=CH, 3-NO2; X=CH=CH, 2-NO2, which is carried out under the action of 200 mol% glucose in the presence of sodium hydroxide in a water-ethanol medium at 50 °C for 1 hour.
EFFECT: expanding the range of methods for obtaining carboxyl-containing azoxybenzenes used as multi-purpose organic compounds.
1 cl, 4 ex
Title | Year | Author | Number |
---|---|---|---|
METHOD OF PRODUCING N-ADAMANTYLATED AMIDES | 2013 |
|
RU2549901C1 |
METHOD OF PRODUCING (1-ADAMANTYL)FURANES | 2017 |
|
RU2661482C1 |
METHOD FOR PRODUCING A NEOCUPROIN DERIVATIVE | 2022 |
|
RU2799334C1 |
METHOD FOR PRODUCING 1,3-DIOXACYCLOALKYL-CONTAINING AZOXIDES | 2021 |
|
RU2767880C1 |
METHOD OF PRODUCING ADAMANTYL-CONTAINING β-DICARBONYL COMPOUNDS | 2012 |
|
RU2496766C1 |
METHOD FOR OBTAINING HYDROXYALKYL-CONTAINING AZOOXIDES | 2021 |
|
RU2769996C1 |
METHOD FOR PRODUCING 2-HYDROXY-2-((5-METHYLFURAN-2-YL)METHYL)-3,3,3-TRIFLUOROPROPANOIC ACID | 2023 |
|
RU2813205C1 |
METHOD OF PRODUCING 1,3-DICARBONYL COMPOUNDS CONTAINING DIBENZOSUBERENYL FRAGMENT | 2014 |
|
RU2560727C1 |
METHOD OF PRODUCING 2-(AMINOALKYL)-3-(AMINOPHENYL)BICYCLO[2,2,1]HEPTANES | 2012 |
|
RU2493145C1 |
METHOD OF OBTAINING 1-ALKYNYL ADAMANTANES | 2012 |
|
RU2507189C1 |
Authors
Dates
2023-01-25—Published
2022-05-05—Filed