FIELD: chemistry.
SUBSTANCE: method is carried out via adamantylation of nitrogen-containing compounds with 1-adamantane in the presence of a Lewis acid in the form of aluminium triflate in amount of 5 mol %, in a medium of boiling nitromethane with a stoichiometric radio of reactants. The nitrogen-containing compounds used are primary amides of carboxylic acids or primary amides of sulphonic acids.
EFFECT: obtaining the desired compounds with good output using environmentally friendly and commercially available reactants.
3 cl, 7 ex
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Authors
Dates
2015-05-10—Published
2013-12-30—Filed