FIELD: electrometallurgy.
SUBSTANCE: production of magnesium with a zero degree of oxidation. The method includes electrolysis of an aqueous solution of magnesium chloride using a cathode coated with a polyaniline film and an anode made of graphite. The concentration of magnesium ions in an aqueous solution is between 300 mg/l and 7 g/l, and the total concentration of other dissolved salts does not exceed 50 g/l. At the same time, during the process, the temperature of the solution is maintained in the range between +1°C to +4°C, the DC voltage is 3.0-31.0 V, and the current strength is 1 A-10 A, ensuring transition of magnesium ions to the zero-oxidation state at the cathode with a polyaniline film and retention of small fragments of formed magnesium in the polyaniline film.
EFFECT: extraction of up to 75% of magnesium is enabled.
1 cl, 2 dwg, 1 ex
Title | Year | Author | Number |
---|---|---|---|
METHOD FOR PRODUCING LITHIUM BY ELECTROLYSIS FROM AQUEOUS SOLUTIONS CONTAINING LITHIUM IONS | 2020 |
|
RU2742097C1 |
METHOD OF PRODUCTION OF HIGH-PURITY LITHIUM HYDROXIDE FROM NATURAL BRINES | 1998 |
|
RU2157338C2 |
METHOD OF RECYCLING SPENT CHEMICAL CELLS | 2011 |
|
RU2486262C2 |
METHOD FOR ELECTROCHEMICAL OXIDATION OF BROMIDE TO BROME | 2003 |
|
RU2316616C2 |
METHOD OF EXTRACTING BROMINE FROM NATURAL WATER TO OBTAIN METAL BROMIDES | 2008 |
|
RU2398734C2 |
METHOD OF PRODUCING HIGH-PURITY LITHIUM HYDROXIDE AND HYDROCHLORIC ACID | 2009 |
|
RU2470861C2 |
METHOD FOR OBTAINING LITHIUM HYDROXIDE MONOHYDRATE OF HIGH PURITY FROM MATERIALS CONTAINING LITHIUM SALTS | 2021 |
|
RU2769609C2 |
METHOD OF PRODUCTION OF METALS BY ELECTROLYSIS OF THE MOLTEN SALTS | 2004 |
|
RU2274680C2 |
ELECTROLYZER, METHOD OF PREPARATION OF BASE SOLUTION AND SOLUTION CONTAINING ACID, AND METHOD OF PREPARATION OF BASE SOLUTION AND SOLUTION OF PURE ACID | 1992 |
|
RU2107752C1 |
METHOD FOR RECOVERING BROMINE OUT OF BROMINE-CONTAINING SOLUTIONS AND INSTALLATION FOR PERFORMING THE SAME | 1998 |
|
RU2171862C2 |
Authors
Dates
2023-03-22—Published
2022-01-14—Filed