FIELD: chemical technology.
SUBSTANCE: invention relates to a method for purifying air from volatile organic compounds (VOCs), in particular amines, specifically to a method for purifying air from diethylamine. The method of air purification from diethylamine by its adsorption and complete oxidation includes contacting air with a catalyst during heating. As a catalyst, a system based on lanthanum cobaltite of the formula LaCoO3 with a perovskite structure deposited on a carrier (zirconium oxide doped with lanthanum) is used, characterized by a porous structure with a specific surface area of 72 m2/g, a mesopore volume of 0.183 cm3/g. The ratio of components, wt.%: LaCoO3 - 20, the rest is the carrier. Next, air containing diethylamine impurities is contacted with a catalyst during microwave heating of the catalyst layer with a radiation power and frequency of 50 W and 3.8 GHz, respectively, at a temperature of 100-200°C and volumetric feed rate of raw materials 6000 h-1.
EFFECT: complete purification (100%) of air from diethylamine and reduction of process temperature to 100°C due to the adsorption of diethylamine at this temperature and its complete oxidation when the temperature rises to 200°C, which is significantly lower compared to the prototype due to the use of microwave heating of the catalyst composition LaCoO3 (20%)/ZrO2-La.
1 cl, 5 ex
| Title | Year | Author | Number | 
|---|---|---|---|
| METHOD FOR CLEANING AIR FROM ETHANOL | 2023 | 
 | RU2798584C1 | 
| METHOD FOR CLEANING AIR FROM ETHANOL | 2023 | 
 | RU2802012C1 | 
| METHOD OF PREPARING CATALYST FOR COMPLETE OXIDATION OF HYDROCARBONS, CATALYST PREPARED USING SAID METHOD, AND METHOD OF PURIFYING AIR FROM HYDROCARBONS USING OBTAINED CATALYST | 2013 | 
 | RU2515510C1 | 
| CATALYST FOR PRODUCING SYNTHESIS GAS PRODUCTION AND METHOD FOR PRODUCING SYNTHESIS GAS USING SAID CATALYST | 2022 | 
 | RU2784334C1 | 
| CATALYST, CATALYST CARRIER, METHODS OF THEIR PRODUCTION(VERSIONS) AND METHOD OF EXHAUST GASES CLEANING FROM NITROGEN OXIDES | 2001 | 
 | RU2192307C1 | 
| METHOD FOR PRODUCING CO SYNTHESIS GAS | 2017 | 
 | RU2668863C1 | 
| CATALYST COMPOSITION AND METHOD FOR USE IN SELECTIVE CATALYTIC REDUCTION OF NITROGEN OXIDES | 2012 | 
 | RU2608616C2 | 
| METHOD OF PREPARING CATALYST FOR OXIDATIVE CONDENSATION OF METHANE, CATALYST PREPARED USING SAID METHOD, AND METHOD FOR OXIDATIVE CONDENSATION OF METHANE USING OBTAINED CATALYST | 2013 | 
 | RU2515497C1 | 
| METHOD OF PRODUCING PEROVSKITES | 2009 | 
 | RU2440292C2 | 
| CATALYST FOR REMOVAL OF SULPHUR OXIDES FROM FLUE GASES OF POWER PLANTS | 2019 | 
 | RU2729422C1 | 
Authors
Dates
2023-05-31—Published
2023-04-04—Filed