IRON-CONTAINING CATALYST COMPONENT FOR POLYMERIZATION OF ETHYLENE INTO HIGH-LINEAR POLYETHYLENE, THERMOSTABLE CATALYST AND METHOD FOR ITS PREPARATION Russian patent published in 2023 - IPC C07F15/02 C08F4/602 C08F110/02 

Abstract RU 2805919 C1

FIELD: polymerization.

SUBSTANCE: component of an ethylene polymerization catalyst, namely {2-[1-(2,4-bis-(diphenylmethyl)-6-cycloalkylphenylimino)ethyl]-6-[1-(2,4,6-trimethylphenylimino)- ethyl]-pyridine}iron(II) dichloride having the structure represented by the general formula 1, in which the cycloalkyl substituent is selected from the group consisting of cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, cycloheptyl, cyclooctyl, cyclononyl, cyclodecyl, cycloundecyl and cyclododecyl, i.e. integer n = 1…10. Also proposed is a catalyst for the polymerization of ethylene, including a compound of general formula 1, a method for preparing the catalyst and its use for the polymerization of ethylene.

EFFECT: production of a catalyst component and an ethylene polymerization catalyst containing this component, the temperature maximum of which is in the range of 60-70°C, which makes it possible to obtain highly linear polyethylene without terminal vinyl groups with an MW of 7.5-306 kg/mol, MWD of 2.0-16, melting point of 128-136°C.

10 cl, 1 tbl, 34 ex

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RU 2 805 919 C1

Authors

Oleinik Ivan Ivanovich

Oleinik Irina Vladimirovna

Sun Ven-Khua

Dates

2023-10-24Published

2023-01-24Filed