FIELD: organic chemistry, chemical technology. SUBSTANCE: tetrafluoroethylene or hexafluoropropylene is fluorinated with a mixture consisting of cobalt trifluoride and difluoride at continuous regime at 100-380 C. Concentration of cobalt trifluoride in mixture is maintained at the range 50-80 wt. -%. Content of basic substance in the synthesized product is 99.1-99.6%. Output of process is 1.9-6.5 l/h the parent perfluoroalkene/1 l reaction volume. The synthesized compounds can be used in chemical industry for production of coolant-166 and -218. EFFECT: improved method of synthesis, increased purity and yield of products. 2 cl, 1 tbl
| Title | Year | Author | Number | 
|---|---|---|---|
| METHOD OF PREPARING PERFLUOROALKANE OF ETHANE OR PROPANE SERIES | 1996 | 
 | RU2155178C2 | 
| METHOD OF SYNTHESIS OF OCTAFLUOROPROPANE AND REACTOR FOR ITS EMBODIMENT | 2000 | 
 | RU2185363C2 | 
| METHOD OF PREPARING 1,1,1,2-TETRAFLUOROETHANE (COOLANT- 134a) | 1997 | 
 | RU2132839C1 | 
| METHOD OF PREPARING PERFLUOROALKANES | 1997 | 
 | RU2135451C1 | 
| HEXAFLUOROETHANE AND/OR OCTAFLUOROPROPANE PRODUCTION PROCESS | 2002 | 
 | RU2224736C1 | 
| METHOD OF PREPARING HEXAFLUOROETHANE | 1997 | 
 | RU2124493C1 | 
| METHOD OF 1,1-DIFLUOROETHANE REFINING | 1995 | 
 | RU2098399C1 | 
| METHOD OF SYNTHESIS OF PENTAFLUOROETHANE (COOLANT-125) | 1999 |  | RU2165919C1 | 
| METHOD OF SYNTHESIS OF OCTAFLUOROPROPANE AND A REACTOR FOR ITS REALIZATION | 1992 | 
 | RU2041194C1 | 
| METHOD OF OCTAFLUOROPROPANE SYNTHESIS | 1984 | 
 | RU1630241C | 
Authors
Dates
1997-12-27—Published
1995-11-29—Filed