FIELD: nonferrous metallurgy; applicable in electrochemical recovery of noble metals. SUBSTANCE: method includes neutralization of aqueous solution after extraction processing of noble metals, for instance, raffinate after extraction of platinum and palladium up to residual acidity of 20-30 g/l of HCl. Solution is treated in electrolyzer on flat titanium cathode with current density of 1500-2000 A/sq.m and voltage of 8-12 V. Formed in process of electroflotocoagulation occurring in electrolyzer are hydroxides of base metals on which organic substance found in solution are adsorbed. Organic substances include extracting agents and solvents, for instance, tributyl phosphate, kerosene, octanol, etc. Purified solution contains traces of inorganic impurities and organic matter. For this solution, noble metals are deposited on three-dimensional cathode made of graphite material. EFFECT: higher efficiency due to processing of solutions obtained in extraction processing of noble metals, increased recovery and purity of final product. 3 cl, 1 tbl, 3 ex
Title | Year | Author | Number |
---|---|---|---|
METHOD OF PREPARING AMMONIUM CHLORIRIDEATE | 2000 |
|
RU2161131C1 |
METHOD OF RECOVERY OF NOBLE METALS FROM SOLUTION OF HYDROCHLORIC ACID | 1998 |
|
RU2131485C1 |
METHOD OF RECOVERING AND SEPARATING PLATINUM-GROUP METALS | 2002 |
|
RU2200132C1 |
METHOD OF RECOVERY AND SEPARATION OF PLATINUM GROUP METALS | 2000 |
|
RU2161130C1 |
METHOD OF RECOVERING AND PURIFYING PLATINUM GROUP METALS AND GOLD | 1997 |
|
RU2108294C1 |
METHOD OF RECOVERING PALLADIUM FROM HYDROCHLORIC ACID SOLUTION | 1998 |
|
RU2130429C1 |
METHOD OF RECOVERING AND SEPARATING PLATINUM AND PALLADIUM | 1998 |
|
RU2121517C1 |
METHOD OF PREPARING PLATINUM GROUP METALS FROM TIN- CONTAINING SOLUTION | 1999 |
|
RU2156818C1 |
METHOD OF EXTRACTION OF PALLADIUM | 2000 |
|
RU2161129C1 |
RHODIUM REFINING METHOD | 2022 |
|
RU2797800C1 |
Authors
Dates
2001-03-27—Published
2000-01-26—Filed