FIELD: organic synthesis. SUBSTANCE: invention relates to preparation of 5,5'-(oxydi)pentan-2-one, which can be used as multifunctional solvent, extractant, fragrance compound, and as raw material for synthesis of heterocyclic compounds. Method consists in reaction of acetylcyclopropane with water in diethyl ether medium in presence of copper-containing catalyst, in particular CuCl2•H2O or CuBr2 at acetylcyclopropane/catalyst/water molar ratio 1:(0.005-0,01):5 and temperature 180-200 C. Reaction time 6-10 h, yield of product 50-64%. EFFECT: enlarged assortment of various-destination organics. 1 tbl, 4 ex
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Authors
Dates
2003-01-27—Published
2000-06-02—Filed