FIELD: chemistry of organometallic compounds, catalysts.
SUBSTANCE: invention relates to bridge metallocene compounds consisting of indenylcyclopentadienyl groups of the formula (I): , wherein R1 and R2 mean hydrogen atom (H), linear, branched, cycloaliphatic or aromatic hydrocarbon (C1-C20)-group, any adjacent pairs R3, R4, R5, R6 are joined with formation of saturated or unsaturated cyclic (C4-C20)-structure including the bond of cyclopentadienyl ring; M means zirconium; X1 and X2 mean anion bound with metal M, or they are bound to one another with formation of (C4-C7)-cycle. Indicated compounds can be used successfully as components of catalyst used for polymerization of olefins.
EFFECT: improved preparing method, improved polymerization method, enhanced properties of catalysts.
14 cl, 2 tbl, 12 ex
Title |
Year |
Author |
Number |
METALLOCENES, METHOD OF THEIR SYNTHESIS, POLYMERIZATION CATALYST, METHOD OF, POLYMERIZATION OF OLEFINS, HOMOPOLYMERS AND PROPYLENE COPOLYMER |
1996 |
- Reskoni Luidzhi
- P'Emontezi Fabritsio
- Nifant'Ev I.E.
- Ivchenko P.V.
|
RU2177948C2 |
CATALYST(S) FOR COPOLYMERIZATION OF OLEFINS, METHOD OF PREPARING OLEFIN HOMO OR COPOLYMERS |
1993 |
- Luidzhi Reskoni
- Mauritsio Galimberti
- Fabritsio P'Emontesi
- Floriano Gal'El'Mi
- Ehnriko Al'Bitstsati
|
RU2132229C1 |
CATALYST COMPOSITION, METALLOCENE COMPLEX AND METHOD OF POLYMERIZATION OF OLEFINS |
1994 |
|
RU2156253C2 |
CATALYST COMPOSITION USED FOR OLEFIN POLYMERIZATION |
1993 |
- Kristin Zhaklin Shabran
- Jan Rejmond Littl
- Dzhon Pol Maknelli
|
RU2126424C1 |
CATALYTIC SYSTEM FOR (CO)POLYMERIZATION OF ALPHA-OLEFINS |
1996 |
- Roberto Fusko
- Luka Longo
- Antonio Proto
- Diego Vil'Jarolo
- Dzhanfranko Gul'El'Metti
- Liliana Dzhila
|
RU2174986C2 |
METALLOCENE COMPOUNDS, METHOD FOR THEIR PREPARING, CATALYST FOR POLYMERIZATION OF OLEFINS, METHOD FOR POLYMERIZATION |
2000 |
- Juehn Dzhon A.
- Ehlder Majkl Dzh.
- Dzhounz Robert L.
|
RU2245341C2 |
CATALYST COMPOSITION USED FOR POLYMERIZATION OF OLEFINS |
1993 |
- Jan Rejmond Littl
- Dzhon Pol Maknelli
|
RU2165435C2 |
BRIDGE-BOUND METALLOCENES, METHOD FOR POLYMERIZATION |
1999 |
|
RU2232766C2 |
CATALYSIS AND METHODS OF POLYMERIZATION OF OLEFINS |
1995 |
- Dall' Otstso Titsiano
- Galimberti Mauritsio
- Reskoni Luidzhi
- Al'Bitstsati Ehnriko
- Pennini Dzhanni
|
RU2155774C2 |
METHOD OF POLYMERIZATION OF ALPHA-OLEFIN, AND CATALYST FOR PREPARING ALPHA-OLEFIN |
1995 |
- Ehzerton Brehdli P.
- Nad' Shandor
|
RU2164228C2 |