FIELD: analytical methods.
SUBSTANCE: ms comprises preparing gold(III) solution, converting gold into complex compound with the aid of sorbent (in particular, silica gel) chemically modified with dipropyldisulfide groups, treating sorbent with water-ethanol solution of Michler thioketone, and measuring coefficient of diffuse reflection of surface gold(I) complex at 540nm. Specifically, silica gel chemically modified with dipropyldisulfide groups is added to gold(III)-containing solution. Mixture is vigorously stirred for 5 min, sorbent is separated from solution by decantation. Ten milliliters of 1-10-5 to 1-10-4 M solution of Michler thioketone in 50% ethanol are poured onto thus separated sorbent, the total stirred for 5 min, sorbent is removed, placed in fluoroplastic cuvette, and coefficient of diffuse reflection at 540nm is measured. Method can be employed when determining gold in process solutions, gold-bearing ores and ore concentrates as well as in processing products thereof.
EFFECT: simplified procedure and lowered detection limit.
2 tbl, 4 ex
| Title | Year | Author | Number | 
|---|---|---|---|
| METHOD FOR DETECTING SILVER | 2005 | 
 | RU2287157C1 | 
| METHOD FOR DETECTING PALLADIUM | 2005 | 
 | RU2287156C1 | 
| COPPER DETERMINATION METHOD | 2005 | 
 | RU2291422C1 | 
| METHOD OF DETERMINING PALLADIUM (II) | 2010 | 
 | RU2426986C1 | 
| METHOD FOR PHOTOMETRIC DETERMINATION OF PLATINUM (II) | 2015 | 
 | RU2593009C1 | 
| METHOD OF DETERMINING COPPER (I) | 2021 | 
 | RU2768614C1 | 
| METHOD FOR DETERMINING IRON (III) | 2020 | 
 | RU2755633C1 | 
| METHOD FOR PHOTOMETRIC DETERMINATION OF RHENIUM (VII) | 2015 | 
 | RU2615613C1 | 
| METHOD OF DETERMINING BISMUTH | 2004 | 
 | RU2255334C1 | 
| RUTHENIUM DETECTION METHOD | 2005 | 
 | RU2287155C1 | 
Authors
Dates
2006-06-27—Published
2005-01-11—Filed