FIELD: chemistry.
SUBSTANCE: invention concerns chemistry of adamantine derivatives, particularly a new method for obtaining 1,3-di(4-R-phenylseleno)adamantanes of the general formula 
, which can be of interest as semiproducts in synthesis of some biologically active substances. The method involves reaction for producing 1,3-di(4-R-phenylseleno) adamantanes by adjunction of di-(4-R)-phenylselenides, i.e. bis-phenylselenide or bis-4-chlorphenylselenide, to 1,3-dehydroadamantane or 5,7-dimethyl-1,3-dehydroadamantane respectively at equimolar reagent ratios in absolute diethyl ether medium at temperature of 34-40°C for 0.5-1 hours.
EFFECT: expanded range of chemical compounds, particularly of new 1,3-di(4-R-phenylseleno)adamantanes with high yield.
1 cl, 4 ex
| Title | Year | Author | Number | 
|---|---|---|---|
| METHOD OF PRODUCING 1,3-DI(R-THIO)ADAMANTANES | 2011 | 
									
  | 
                RU2448956C1 | 
| METHOD OF PRODUCING 1,3-DI(R-THIO)ADAMANTANES | 2011 | 
									
  | 
                RU2448955C1 | 
| METHOD OF PREPARING 1-(4-R-ARYL)ADAMANTANES AND DERIVATIVES THEREOF | 2006 | 
									
  | 
                RU2307116C1 | 
| METHOD OF OBTAINING ADAMANTYL CONTAINING DERIVATIVES OF 1,4-DIKETONES | 2006 | 
									
  | 
                RU2330013C1 | 
| METHOD OF SYNTHESIS OF α-ADAMANTYL-CONTAINING ALIPHATIC AND SATURATED AROMATIC KETONES | 2000 | 
									
  | 
                RU2186760C2 | 
| METHOD FOR PREPARING 3-HALOGEN-1-(ETHOXYCARBONYL)-ALKYLADAMANTANES | 2006 | 
									
  | 
                RU2301796C1 | 
| METHOD OF OBTAINING DIALKYLAMIDES OF 3-BROME-1-ADAMANTILALKANCARBON ACIDS | 2007 | 
									
  | 
                RU2344122C1 | 
| METHOD OF SYNTHESIS OF ADAMANTYL-CONTAINING β-DIKETONES AND KETOESTERS | 2000 | 
									
  | 
                RU2187493C1 | 
| METHOD OF OBTAINING N,N-DIALKYL-SUBSTITUTED AMIDES OF ADAMANTYLALKYLCARBOXYLIC ACIDS | 2007 | 
									
  | 
                RU2348611C1 | 
| METHOD FOR PREPARING ADAMANTYL-CONTAINING NITRILES | 2003 | 
									
  | 
                RU2240310C1 | 
Authors
Dates
2008-09-10—Published
2007-03-14—Filed