FIELD: chemistry.
SUBSTANCE: invention relates to the chemistry of adamantane derivatives, specifically to a method of producing 1,3-di(R-thio)adamantanes of general formula: , where (1); (2); (3); (4). The method involves binding disulphides to 1,3-dehydroadamantane, said disulphides being selected from: diphenyl disulphide, n,n'-bis-(4-bromophenyl)disulphide, 2,2'-dibenzthiazolyl disulphide, n,n'-bis-(4-aminophenyl)disulphide with molar ratio of reactants equal to 1:1.1, in the medium of an inert solvent, e.g., diethyl ether, tetrahydrofuran or methylene chloride, in the presence of catalytic amounts of sodium hydroxide at temperature 35-65°C for 2-3 hours.
EFFECT: novel single-step method of producing 1,3-di(R-thio)adamantanes, which enables to obtain disclosed compounds with high output.
1 cl, 4 ex
Title | Year | Author | Number |
---|---|---|---|
METHOD OF PRODUCING 1,3-DI(R-THIO)ADAMANTANES | 2011 |
|
RU2448955C1 |
METHOD FOR OBTAINING 1,3-DI(4-R-PHENYLSELENO)ADAMANTANES | 2007 |
|
RU2333214C1 |
METHOD OF PREPARING 1-(4-R-ARYL)ADAMANTANES AND DERIVATIVES THEREOF | 2006 |
|
RU2307116C1 |
METHOD OF SYNTHESIS OF α-ADAMANTYL-CONTAINING ALIPHATIC AND SATURATED AROMATIC KETONES | 2000 |
|
RU2186760C2 |
METHOD OF PRODUCING 1-ADAMANTYL ISOTHIOCYANATE | 2014 |
|
RU2551682C1 |
METHOD OF OBTAINING ADAMANTYL CONTAINING DERIVATIVES OF 1,4-DIKETONES | 2006 |
|
RU2330013C1 |
METHOD FOR PREPARING ADAMANTYL-CONTAINING AROMATIC COMPOUNDS | 2006 |
|
RU2309932C1 |
METHOD OF OBTAINING ADAMANTYLPHENYL ETHERS | 2007 |
|
RU2346927C1 |
METHOD FOR PREPARING ADAMANTYL-CONTAINING NITRILES | 2003 |
|
RU2240310C1 |
METHOD OF OBTAINING N,N-DIALKYL-SUBSTITUTED AMIDES OF ADAMANTYLALKYLCARBOXYLIC ACIDS | 2007 |
|
RU2348611C1 |
Authors
Dates
2012-04-27—Published
2011-02-01—Filed