FIELD: chemistry.
SUBSTANCE: invention concerns method of obtaining adamantylphenyl ethers of the general formula: R1=R2=H, R3=CH3 (1); R1=OH, R2=R3=H (2); R1=R3=H, R2=OH (3); R1=R2=H, R3=OH (4); R1=R2=H, R3=NO2 (5); R1=OCH3 R2=H,R3=C2H5 (6), which are semiproducts for bioactive substance synthesis. Method involves interaction of adamantane derivative with phenol derivative. 1,3-dehydroadamantane is used as adamantane derivative, and compounds from the range of n-cresol, pyrocatechin, resorcin, hydroquinone, n-nitrophenol, 4-ethylguaiacol are used as phenol derivative, at component mol ratio of 1:(1.5-2) in diethyl ether medium at its boiling temperature for 20-30 minutes.
EFFECT: high output of adamantylphenyl ethers.
6 ex
Title | Year | Author | Number |
---|---|---|---|
METHOD OF OBTAINING ADAMANTYL CONTAINING PHENOL DERIVATIVES | 2006 |
|
RU2326104C1 |
METHOD FOR PREPARING ADAMANTYL-CONTAINING DERIVATIVES OF NAPHTHALENE | 2006 |
|
RU2309933C1 |
METHOD FOR PREPARING ADAMANTYL-CONTAINING AROMATIC COMPOUNDS | 2006 |
|
RU2309932C1 |
METHOD OF SYNTHESIS OF ADAMANTYL-CONTAINING β-DIKETONES AND KETOESTERS | 2000 |
|
RU2187493C1 |
METHOD OF PRODUCING 1-ADAMANTYL ISOTHIOCYANATE | 2014 |
|
RU2551682C1 |
METHOD OF PRODUCING 1-ADAMANTYL ISOCYANATE | 2014 |
|
RU2551681C1 |
METHOD OF PRODUCING ADAMANTYL ESTERS OF UNSATURATED ACIDS | 2010 |
|
RU2448950C1 |
METHOD FOR PREPARING (ADAMANT-1-YLMETHYLENE)-CONTAINING AROMATIC COMPOUNDS | 2006 |
|
RU2309931C1 |
METHOD OF PREPARING 1-(4-R-ARYL)ADAMANTANES AND DERIVATIVES THEREOF | 2006 |
|
RU2307116C1 |
METHOD FOR PREPARING ALPHA-ADAMANTYL-CONTAINING ALDEHYDES | 2003 |
|
RU2240303C1 |
Authors
Dates
2009-02-20—Published
2007-07-09—Filed