FIELD: metallurgy.
SUBSTANCE: invention relates to refractory compositions metallurgy and may be used as ceramics and protective covering in high-temperature facilities. The original mixture of titanium and boron chlorides containing 3-5% of boron chloride excess from stoichiometry is recovered by sodium in argon environment. The original mixture temperature is maintained within the interval from 0 to 10°C. The resulting reaction mass is grinded and leached in hydrochloric acid solution.
EFFECT: synthesised titanium diboride with grain size being 30-50 nm and stoichiometric composition is characterised with improved process parametres.
1 tbl, 1 ex
| Title | Year | Author | Number |
|---|---|---|---|
| ELECTROCHEMICAL METHOD OF PRODUCING TITANIUM DIBORIDE NANOPOWDERS | 2011 |
|
RU2465096C1 |
| RECYCLING TITANIUM DIBORIDE MATERIALS | 2013 |
|
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| METHOD OF PRODUCING TITANIUM BORIDE POWDER | 2018 |
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| METHOD OF PRODUCING COMPOSITE NANOPOWDER ZrB - SiC | 2023 |
|
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| METHOD OF PRODUCING TITANIUM BORIDE POWDER | 2015 |
|
RU2603407C1 |
| METHOD OF OBTAINING ALUMINIUM DODECABORIDE | 2012 |
|
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| METHOD FOR LOW-TEMPERATURE SYNTHESIS OF TITANIUM DIBORIDE | 2019 |
|
RU2723859C1 |
| METHOD OF PRODUCTION OF POWDER-LIKE ZIRCONIUM DIBORIDE | 2004 |
|
RU2309893C2 |
| METHOD OF PRODUCTION OF FINE SINGLE-CRYSTAL POWDER OF METAL DIBORIDE | 1995 |
|
RU2087262C1 |
| METHOD OF MAKING BORON-SILICON-CONTAINING NANOPARTICLES | 2011 |
|
RU2460689C1 |
