FIELD: physics.
SUBSTANCE: when determining quality of a photovoltaic junction, a p-n junction is illuminated with monochromatic light with wavelength λ defined by the expression:
where Eg is the band gap of the semiconductor, Ev; Eg.top is the band gap of the semiconductor of the (z-1)th p-n junction in the solar cell (z is an index number counted from the exposed surface of the p-n junction whose quality is being determined) when z ≥ 2; Eg.top = 1.4 Eg eV, when z = 1. Intensity P of illumination is changed and the resultant open-circuit voltage Voc is measured for each value of P and the obtained relationship between Voc and P is approximated. Values of recombinanation and diffusion photovoltaic parametres P0r and P0d are determined from the obtained approximated relationship. Forward-bias current with varying density J is then passed through the p-n junction. Intensity of the generated boundary electroluminescence L is measured for each value of J and the relationship between L and J is approximated. From the obtained approximated relationship, values of recombinanation and diffusion electroluminescence parametres kr and kd are found and the quality of the photovoltaic p-n junction is determined from the value of recombination saturation current density J0r and diffusion saturation current density J0d.
EFFECT: possibility of diagnosing a photovoltaic p-n junction which is part of a multijunction solar cell.
3 dwg
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Authors
Dates
2009-12-10—Published
2008-08-12—Filed