HYDROFORMYLATION PROCESS STABILISATION Russian patent published in 2010 - IPC C07C47/02 C07C45/50 G05D13/00 G05D16/00 G05D23/00 G05D27/00 B01J12/00 

Abstract RU 2388742 C2

FIELD: chemistry.

SUBSTANCE: present invention relates to versions of a method of stabilising the hydroformylation process and a device for realising the said method. One version of the method involves reaction of one or more reagents, carbon monoxide and hydrogen in the presence of a hydroformylation catalyst to obtain an exhaust gas stream and a reaction product stream which contains one or more products, in which the method described above is realised at such partial pressure of carbon monoxide that, the rate of reaction increases when partial pressure of carbon monoxide falls, and falls when partial pressure of carbon monoxide increases; and in which the following steps of the process for stabilising the rate of reaction, total pressure, speed of the exhaust gas stream, reaction temperature or combinations thereof are carried out, process steps including at least one of the following process control schemata, selected from: Scheme A: (a1) setting a given total pressure; (a2) determination of total pressure and determination of the difference between the measured total pressure and the given total pressure; and (a3) based on the pressure difference measured at step (a2), manipulation of the stream of incoming gas which contains carbon monoxide in order to balance the measured total pressure to virtually the given total pressure; and Scheme B: (b1) setting a given speed of the exhaust gas stream; (b2) determination of the speed of the exhaust gas stream and determination of the difference between the measured speed of the exhaust gas stream and the given speed of the exhaust gas stream; and (b3) manipulation of the speed of incoming gas which contains carbon monoxide based on the difference in the speed of the exhaust gas stream measured at step (b2) in order to equalise the determined speed of the exhaust gas stream virtually with the given speed of the exhaust gas stream.

EFFECT: design of an efficient method of stabilising the hydroformylation process.

26 cl, 2 tbl, 20 dwg, 7 ex

Similar patents RU2388742C2

Title Year Author Number
REGULATION OF RATIO ALDEHYDE OF NORMAL STRUCTURE: ALDEHYDE OF ISO-STRUCTURE IN PROCESS OF HYDROFORMYLATION WITH MIXED LIGAND BY REGULATION OF SYNTHESIS-GAS PARTIAL PRESSURE 2010
  • Ajzenshmid Tomas K.
  • Sori Dzheffri S.
  • Miller Glenn A.
  • Brehmmer Majkl A.
RU2546110C2
METHOD FOR HYDROFORMYLATION WITH IMPROVED CONTROL OVER PRODUCT ISOMERS 2008
  • Ajzenshmid Tomas K.
  • Peterson Ronal'D R.
  • Miller Glenn A.
  • Abatdzhoglou Ehntoni G.
RU2458906C2
CATALYST PRODUCTION METHOD 2013
  • Bremmer Majkl A.
  • Uotson Rik B.
  • Uotkins Ejveri L.
RU2639874C2
HYDROFORMYLATION METHOD 2015
  • Brammer Majkl A.
  • Fillips Dzhordzh R.
  • Ajzenshmid Tomas K.
  • Koks Irvin B.
  • Khetterli Robert
  • Bajnbridzh Majkl Dzhon
RU2699368C2
METHODS TO STORE TRANSITION METAL ORGANOPHOSPHOROUS LIGAND BASED CATALYSTS 2012
  • Ajzenshmid Tomas K.
  • Bekker Mikhael K.
  • Kempbell Donald L.
  • Bremmer Majkl A.
  • Miller Glenn A.
  • Lord Edrian
  • Rudolf Jens
  • Re Khans-Ryudiger
RU2598386C2
METHOD OF HYDROFORMYLATION BY MEANS OF DOUBLE OPEN-END BISPHOSPHITE LIGAND 2009
  • Brehmmer Majkl A.
RU2541537C2
METHODS FOR CONVERTING OLEFINS INTO ALCOHOLS, ESTERS, OR COMBINATIONS THEREOF 2017
  • Beker Majkl K.
  • Brammer Majkl A.
  • Dzhajlz Dzhejson F.
  • Miller Glenn A.
  • Fillips Dzhordzh R.
  • Vatson Rik B.
  • Vamberg Stefani
  • Smidt Martin Lukas
RU2751511C2
METHODS FOR SLOWING CATALYST DEACTIVATION AND/OR SLOWING TETRAPHOSPHIN LIGAND CONSUMPTION IN HYDROFORMYLATION PROCESSES 2019
  • Brammer, Majkl A.
  • Beker, Majkl K.
  • Felsted, Ii, Uilyam N.
RU2795878C2
METHODS FOR REGULATION OF HYDROFORMYLATION PROCESSES 2019
  • Brammer, Majkl A.
  • Tsyan, Khuejfen
RU2788171C2
HYDROFORMYLATION METHOD 2015
  • Miller Glenn A.
  • Eizenshmid Tomas K.
  • Brammer Majkl A.
  • Beker Majkl K.
  • Vatson Rik B.
RU2674698C1

RU 2 388 742 C2

Authors

Peterson Ronal'D R.

Ajzenshmid Tomas S.

Brajant Dehvid R.

Mokhtarzadekh Morteza

Dates

2010-05-10Published

2005-07-19Filed