ETHYLENE OLIGOMERISATION CATALYST Russian patent published in 2011 - IPC B01J31/18 

Abstract RU 2413574 C1

FIELD: chemistry.

SUBSTANCE: invention relates to an ethylene oligomerisation catalyst in form of a mixture of a cocatalyst and a catalyst in molar ratio of 80:1-120:1 in an organic solvent medium. The catalyst used is in form of mononuclear benzothiazole nickel formazans (N1L2) which contain a chloride ion in the ortho- and/or para-position of the phenyl substitute of the formazan ligand (L), of general formula: where R1=C6H4-para-OCH3; C7H15 or C4H9; R2=H or CI; R3=H or Cl. The cocatalyst used is a chlorine-containing organoaluminium compound of general formula AlRnCl3-n, where R=C2H5 or a C4H9 group, and n=1 or 2.

EFFECT: high activity of the catalyst system, which increases output of higher olefins.

3 cl, 1 tbl, 1 dwg

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RU 2 413 574 C1

Authors

Pervova Inna Gennad'Evna

Belov Gennadij Petrovich

Zajdman Aleksej Vjacheslavovich

Lipunov Igor' Nikolaevich

Kajumov Ruslan Rifatovich

Sigejkin Gennadij Ivanovich

Dates

2011-03-10Published

2009-08-07Filed