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2 423 366

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(51)

IPC

C07F3/02(2006-01-01)

(21) (22)

Application

2009125369/04, 2009-07-02

(24)

Start date

2009-07-02

(22)

Actual filing date

2009-07-02

(45)

Published

2011-07-10

(72)

Inventor

Sultanov Rifkat Mukhat'JarovichVasil'Ev Vladimir VladislavovichDzhemilev Usein MemetovichMuslimov Zabir Sabirovich

(73)

Holder

Uchrezhdenie Rossijskoj Akademii Nauk Institut Neftekhimii I Kataliza Ran

METHOD FOR SYNTHESIS OF 2,4,6-TRIPHENYLMAGNESACYCLONONANE Russian patent published in 2011 - IPC C07F3/02

Abstract RU 2423366 C2

FIELD: chemistry.

SUBSTANCE: invention relates to a method for synthesis of 2,4,6-triphenylmagnesacyclononane (I) of formula: .The method involves reaction of styrene with magnesacyclopentane in the presence of a zirconocene dichloride Cp₂ZrCl₂ catalyst. The reaction is carried out in an atmosphere of dry ethylene fed under excess pressure of 0.04 MPa in molar ratio styrene: magnesacyclopentane: Cp₂ZrCl₂=(10-20):10:(0.2-0.4), in a tetrahydrofuran solution at 20-22°C for 8-10 hours.

EFFECT: invention enables to obtain 2,4,6-triphenylmagnesacyclononane of the formula given above.

1 ex, 1 tbl

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RU 2 423 366 C2

Authors

Sultanov Rifkat Mukhat'Jarovich

Vasil'Ev Vladimir Vladislavovich

Dzhemilev Usein Memetovich

Muslimov Zabir Sabirovich

Dates

2011-07-10—Published

2009-07-02—Filed