FIELD: chemistry.
SUBSTANCE: invention relates to a method of producing 2,4,6,8-tetraphenylmagnesacycloundecane of formula I: 
The method involves reaction of styrene with magnesacyclopentane in the presence of a catalyst - zirconocene dichloride Cp2ZrCl2, in a dry argon atmosphere. Molar ratio styrene: magnesacyclopentane: Cp2ZrCl2 = 10:(10-14):(0.3-0.5). The method is carried out in tetrahydrofuran at room temperature (about 20°C) for 12-20 hours.
EFFECT: invention enables to obtain 2,4,6,8-tetraphenylmagnesacycloundecane, which can be used in synthesis of heterocyclic and bifunctional compounds, as well as components for catalyst systems in oligo- and polymerisation of unsaturated hydrocarbons.
1 tbl, 1 ex
| Title | Year | Author | Number |
|---|---|---|---|
| METHOD FOR SYNTHESIS OF 2,4,6-TRIPHENYLMAGNESACYCLONONANE | 2009 |
|
RU2423366C2 |
| METHOD FOR SYNTHESIS OF 2,4-DIPHENYLMAGNESACYCLOHEPTANE | 2009 |
|
RU2423367C2 |
| METHOD FOR SYNTHESIS OF 3,4-DIALKYLMAGNESACYCLOPENTANES | 2009 |
|
RU2423364C2 |
| METHOD OF PRODUCING 2,3,4,5-TETRAALKYLMAGNESACYCLOPENTA2,4-DIENES | 2010 |
|
RU2440354C1 |
| METHOD FOR COMBINED PRODUCTION OF 2,3-DIALKYLMAGNESACYCLOHEPT-2-ENES AND 4,5-DIALKYLMAGNESACYCLOHEPT-4-ENES | 2010 |
|
RU2547265C2 |
| METHOD OF JOINTLY PREPARING 2-ALKYLIDENEMAGNESIUMCYCLOPENTANES AND 2-ALKYL-3-METHYLIDENEMAGNESIUMCYCLOPENTANES | 2003 |
|
RU2245885C1 |
| METHOD OF OBTAINING 1,2,3,3a,4,5,6,7,8,9-DECAHYDROCYCLONONE[b]-MAGNESACYCLOPENTANE | 2007 |
|
RU2342390C1 |
| METHOD OF (9-ETHYL-1-CYCLONONENYL)MAGNESIUM HALOGENIDE OBTAINMENT | 2007 |
|
RU2355696C2 |
| METHOD OF 1, 2, 3, 4, 5, 6, 8, 9, 10, 11, 12, 13-DODECAHYDRO-DICYCLOOCTA-[b, d]-MAGNESACYCLOPENTADIENE PRODUCTION | 2007 |
|
RU2342391C2 |
| METHOD OF PRODUCING 1-BROMO-3-ALKYLBOROLANES | 2012 |
|
RU2507208C1 |
