FIELD: chemistry.
SUBSTANCE: invention relates to chemistry. To obtain sulphuric acid, a starting gas containing SO2, which is obtained in an apparatus for producing sulphuric acid, is passed through at least one reactor in which catalytic oxidation of SO2 to SO3 takes place. The formed SO3 is converted to sulphuric acid. At least a portion of the gas stream containing SO2, coming out of the apparatus for producing sulphuric acid, is hydrogenated with a gas containing H2. The gas stream containing H2S, which is formed during hydrogenation, is fed into a H2S scrubber for obtaining coke gas or into a petrochemical installation. The apparatus for realising the method has an apparatus 1 for producing sulphuric acid, having at least one reactor 9 for catalytic oxidation of SO2 to SO3 and an absorber 12 with sulphuric acid, a further processing section 17 having a hydrogenation reactor 20 into which at least one partial stream of a gas stream 16, coming from the apparatus for producing sulphuric acid, is fed. The apparatus also has a scrubber linked with the section 17, wherein the scrubber is part of the apparatus for cleaning the coke gas.
EFFECT: invention enables to exclude SO2 emission when possible.
12 cl, 2 dwg
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Authors
Dates
2012-07-27—Published
2008-03-20—Filed