FIELD: electrical engineering.
SUBSTANCE: invention relates to a method for fabrication of nickel fibre electrode base with developed fibre structure, intended mainly for chemical current sources and catalysts; according to the said method one performs synthesis of nickel fibres in a water solution containing nickel ions in the presence of an alkali, a pH buffer, a surfactant in the presence of inhomogeneous magnetic field with magnitude equal to 0.01 - 1 T, Nickel ions recovery with a recovery agent proceeds at a temperature of 70 - 160°C during a period of time equal to 0.5 min - 3 h, the ratio of the surfactant introduced being within the range from 8*10-4 M to 5*10-2 M. The nickel fibre electrode base fabricated in accordance with the proposed method possesses developed (up to 12 m2/g) fibre surface consisting of conic-shaped particles, heir height varying within the range from 50 to 2500 nm, the cone aperture angle being 5° - 20°, the cone point curvature radius - 5 - 50 nm, the average distance between the cones - 80 - 1500 nm, the fibres diameter - 0.2 - 20 mcm and/or 60 - 100 nm.
EFFECT: method ensures the possibility to fabricate nickel fibres with preset properties enabling increase of the specific capacity of electrode base made of such fibres.
2 cl, 7 dwg, 1 tbl, 7 ex
Title | Year | Author | Number |
---|---|---|---|
METHOD OF CHARGING ELECTROCHEMICAL CELL WITH AQUEOUS ELECTROLYTE | 2014 |
|
RU2572951C2 |
METHOD OF FABRICATION OF NICKEL OXIDE ELECTRODE FOR NICKEL-ZINC BATTERY | 2014 |
|
RU2543057C1 |
METHOD FOR MANUFACTURING OF OXIDE-NICKEL ELECTRODE FOR ALKALINE ACCUMULATOR | 2009 |
|
RU2407112C1 |
METHOD FOR MANUFACTURING OF FIBRE OXIDE-NICKEL ELECTRODE FOR ALKALINE NICKEL-CADMIUM ACCUMULATOR | 2011 |
|
RU2482569C1 |
HYBRID SUPERCAPACITOR BASED ON NANOSIZED NICKEL HYDROXIDE | 2021 |
|
RU2763028C1 |
METHOD TO MAKE FIBRES OF SILICON OR SILICON-BASED MATERIAL, AND THEIR APPLICATION IN RECHARGEABLE LITHIUM ACCUMULATORS | 2007 |
|
RU2444092C2 |
METHOD FOR MANUFACTURE OF ACTIVE MASS FOR ALKALINE BATTERY OXIDE-NICKEL FIBRE ELECTRODE | 2011 |
|
RU2475895C1 |
ELEMENTAL ANALYSIS METHOD AND DEVICE TO THIS END | 2007 |
|
RU2370755C2 |
METHOD OF MAKING NICKEL OXIDE ELECTRODE | 2009 |
|
RU2406185C1 |
MANUFACTURING PROCESS FOR ALKALI-CELL NICKEL-OXIDE PLATE | 1998 |
|
RU2148284C1 |
Authors
Dates
2013-02-20—Published
2011-05-05—Filed