METHOD OF PRODUCING BINUCLEAR 3,4,5-TRIARYL-1,2-DIPHOSPHACYCLOPENTADIENIDE MANGANESE COMPLEXES Russian patent published in 2014 - IPC C07F9/547 C07F13/00 

Abstract RU 2515559 C1

FIELD: chemistry.

SUBSTANCE: invention relates to a method of producing binuclear 3,4,5-triaryl-1,2-diphosphacyclopentadienide manganese complexes of general formula where Ar=C6H5, para-F-C6H4, para-Cl-C6H4. The method involves reacting a dimer of manganese tetracarbonyl bromide [MnBr(CO)4]2 with 1-trimethylstannyl-3,4,5-triaryl-1,2-diphosphacyclopenta-2,4-diene in molar ratio of 1:2 in pure tetrahydrofuran for 30 minutes at room temperature.

EFFECT: invention increases output of the product and reduces time and power costs.

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RU 2 515 559 C1

Authors

Bezkishko Il'Ja Aleksandrovich

Miljukov Vasilij Anatol'Evich

Sinjashin Oleg Gerol'Dovich

Dates

2014-05-10Published

2013-01-10Filed