FIELD: chemistry.
SUBSTANCE: invention relates to a method of producing binuclear 3,4,5-triaryl-1,2-diphosphacyclopentadienide manganese complexes of general formula where Ar=C6H5, para-F-C6H4, para-Cl-C6H4. The method involves reacting a dimer of manganese tetracarbonyl bromide [MnBr(CO)4]2 with 1-trimethylstannyl-3,4,5-triaryl-1,2-diphosphacyclopenta-2,4-diene in molar ratio of 1:2 in pure tetrahydrofuran for 30 minutes at room temperature.
EFFECT: invention increases output of the product and reduces time and power costs.
3 ex
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Authors
Dates
2014-05-10—Published
2013-01-10—Filed