FIELD: chemistry.
SUBSTANCE: method comprises preparing an alcohol solution of β-diketonates of one or more p-, d- or f-metals with concentration 0.001h2 mol/l; heating the solution to 368-523 K and holding at said temperature for 10-360 minutes to form a metal alkoxo-β-diketonate solution; depositing the obtained solution in droplets at the centre of a substrate being rotated at a rate of 100-16000 rpm, or immersing the substrate into said solution at a rate of 0.1-1000 mm/min at an angle of 0-60° to the vertical; holding the substrate with a film of the alkoxo-β-diketonate solution at 77-523 K until mass loss ceases, to form xerogel on the surface of the substrate; crystallising oxide from the xerogel at 573-1773 K.
EFFECT: invention enables to obtain single- or multilayer dense and porous, amorphous and crystalline nanostructured oxide coatings with ordered particle size ranging from 1 nm to 100 nm with given functional properties.
9 cl, 5 dwg, 10 ex
Title | Year | Author | Number |
---|---|---|---|
METHOD OF OBTAINING NANODISPERSED METAL OXIDES | 2009 |
|
RU2407705C1 |
METHOD FOR PRODUCTION OF THIN FILMS BASED ON INDIUM-TIN OXIDE BY MICRO-PLOTTER PRINTING | 2022 |
|
RU2785983C1 |
METHOD OF OBTAINING FILM COATINGS OF TIN OXIDE ON SUBSTRATES | 2009 |
|
RU2397572C1 |
METHOD FOR OBTAINING HIGHLY-DISPERSIBLE REFRACTORY CARBIDES FOR COATING AND COMPOSITES BASED THEREON | 2007 |
|
RU2333888C1 |
METHOD FOR MODIFICATION OF PHOTONIC CRYSTAL ON THE BASIS OF NANOSTRUCTURED POROUS ANODE OXIDE OF ALUMINUM | 2017 |
|
RU2665498C1 |
METHOD OF OBTAINING NANOSTRUCTURED GAS SENSOR FOR OZONE | 2017 |
|
RU2642158C1 |
METHOD OF SURFACE AND VOLUME PROTECTION OF CERAMIC MATRIX C/SiC AND SiC/SiC-TYPE COMPOSITES | 2006 |
|
RU2322425C1 |
METHOD OF OBTAINING MESOPOROUS NANOSTRUCTURED METAL-OXIDE FILM BY ELECTROSTATIC SPRAYING METHOD | 2016 |
|
RU2646415C1 |
METHOD FOR OBTAINING SOLUTION FUNCTIONAL INK FOR THE FORMATION OF FILMS BASED ON SILVER | 2021 |
|
RU2765126C1 |
METHOD FOR OBTAINING ORIENTED FLUORIDE COATINGS FROM GAS PHASE | 2008 |
|
RU2405857C2 |
Authors
Dates
2014-07-10—Published
2013-02-19—Filed