FIELD: chemistry.
SUBSTANCE: invention relates to a method of producing (1,5,3-dithiazepan-3-yl)-alkanediols. The method includes reacting aminoalkanediol (2-aminopropane-1,3-diol; 2-amino-2-methylpropane-1,3-diol; 3-aminopropane-1,2-diol) with 1-oxa-3,6-dithiacycloheptane in the presence of a SmCl3·6H2O catalyst in the medium of ethanol-chloroform solvents at room temperature for 2.5-3.5 hours. Output of (1,5,3-dithiazepan-3-yl)-alkanediols (1) is 63-78%.
EFFECT: compounds can be used as antioxidant, fungicidal and antimicrobial agents, as well selective complexing agents.
1 tbl, 1 ex
| Title | Year | Author | Number |
|---|---|---|---|
| METHOD OF PRODUCING (1,5,3-DITHIAZEPAN-3-YL)-ALKANEDIOLS | 2013 |
|
RU2559367C2 |
| METHOD FOR OBTAINING N-CYCLOHEXYL-SUBSTITUTED 1,5,3-DITHIAZEPANES | 2014 |
|
RU2574074C1 |
| METHOD OF PRODUCING N-ADAMANTYL-1,5,3-DITHIAZEPANES | 2015 |
|
RU2605447C1 |
| METHOD OF PRODUCING 3-[1-(1-ADAMANTYL)ETHYL]-1,5,3-DITHIAZEPANE AND USE THEREOF AS FUNGICIDALLY ACTIVE AGENT | 2014 |
|
RU2574292C1 |
| METHOD OF PRODUCING 3-(1-ADAMANTYL)-1,5,3-DITIAZEPANE AND USE THEREOF AS FUNGICIDALLY ACTIVE AGENT | 2014 |
|
RU2584692C2 |
| METHOD OF PRODUCING N-CYCLOPENTYL-SUBSTITUTED 1,5,3-DITHIAZEPANES | 2014 |
|
RU2565790C1 |
| METHOD OF PRODUCING N,N-BIS-[(1,5,3-DITHIAZEPAN-3-YL)ALKYL]AMINES | 2014 |
|
RU2591196C2 |
| METHOD OF PRODUCING N-CYCLOALKYL-SUBSTITUTED 1,5,3-DITHIAZEPANES | 2015 |
|
RU2601313C1 |
| METHOD OF PRODUCING (1,5,3-DITHIAZEPAN-3-YL)-QUINOLINES | 2014 |
|
RU2565785C1 |
| METHOD OF PRODUCING METHYL 2-(1,5,3-DITHIAZEPAN-3-YL)ALKANOATES | 2015 |
|
RU2605448C1 |
