FIELD: chemistry.
SUBSTANCE: invention relates to method for obtaining N-cyclohexyl-substituted 1,5,3-dithiazepanes of general formula
where R = 
which consists in interaction of N-cyclohexyl-substituted amine (cyclohexane-amine, tetrahydro-2N-pyrane-4-amine, piperidine-4-amine) with 1-oxa-3,6-dithiacycloheptane in presence of catalyst SmCl3·6H2O in medium of solvents ethanol-chloroform at room temperature for 2.5-3.5 h. Output of N-cyclohexyl-substituted 1,5,3-dithiazepanes (1) constitutes 72-91%.
EFFECT: compounds can find application as fungicidal and antimicrobial agents, as well as selective complexing agents.
1 tbl
| Title | Year | Author | Number |
|---|---|---|---|
| METHOD OF PRODUCING N-CYCLOPENTYL-SUBSTITUTED 1,5,3-DITHIAZEPANES | 2014 |
|
RU2565790C1 |
| METHOD OF PRODUCING N-ADAMANTYL-1,5,3-DITHIAZEPANES | 2015 |
|
RU2605447C1 |
| METHOD OF PRODUCING N-CYCLOALKYL-SUBSTITUTED 1,5,3-DITHIAZEPANES | 2015 |
|
RU2601313C1 |
| METHOD OF PRODUCING 3-[1-(1-ADAMANTYL)ETHYL]-1,5,3-DITHIAZEPANE AND USE THEREOF AS FUNGICIDALLY ACTIVE AGENT | 2014 |
|
RU2574292C1 |
| METHOD OF PRODUCING N,N-BIS-[(1,5,3-DITHIAZEPAN-3-YL)ALKYL]AMINES | 2014 |
|
RU2591196C2 |
| METHOD OF PRODUCING (1,5,3-DITHIAZEPAN-3-YL)-ALKANEDIOLS | 2013 |
|
RU2559359C2 |
| METHOD OF PRODUCING METHYL 2-(1,5,3-DITHIAZEPAN-3-YL)ALKANOATES | 2015 |
|
RU2605448C1 |
| METHOD OF PRODUCING (1,5,3-DITHIAZEPAN-3-YL)-QUINOLINES | 2014 |
|
RU2565785C1 |
| METHOD OF PRODUCING (1,5,3-DITHIAZEPAN-3-YL)-ALKANEDIOLS | 2013 |
|
RU2559367C2 |
| METHOD OF PRODUCING OF BIS-(1,5,3-DITHIAZEPAN-3-IL)CYCLOHEXANES | 2014 |
|
RU2574069C1 |
