FIELD: chemistry.
SUBSTANCE: catalyst contains amorphous substrate based on aluminium oxide or alumosilicate C1-C4-dialkylsuccinate, citric acid, phosphorus and hydrating-dehydrating group, containing element of group VIII base elements and at least one group VIB element. Spectrum of catalyst Raman scattering contains bands 990 and/or 974 cm-1, characteristic for at least one Keggin heteropolyanion, characteristic bands of said succinate and basic characteristic bands of citric acid, with quantity of phosphorus constituting from 0.1 to 20 wt %, quantity of group VIB element(s) constitutes from 5 to 40 wt %, quantity of group VIII element(s) constitutes from 1 to 10 wt %, with quantity of aluminium oxide or alumosilicate in substrate constituting more than 25 wt %, with dialkylsuccinate and citric acid being present in quantity, which corresponds to molar ratio of dialkylsuccinate to group VIB element(s), constituting from 0.15 to 2 mol/mol, and molar ratio of citric acid to group VIB element(s), constituting from 0.05 to 5 mol/mol.
EFFECT: improved hydrodesulphurising and hydrating abilities in comparison with traditional catalysts.
23 cl, 1 tbl, 4 ex
Title |
Year |
Author |
Number |
CATALYST APPLICABLE FOR HYDROPROCESSING, CONTAINING GROUP VIII AND VIB METALS, AND METHOD FOR PRODUCING WITH ACETIC ACID AND DIALKYL(C1-C4)SUCCINATE |
2010 |
- Marshan Karen
- Gishar Bertran
- Din' Mat'E
- Rebejo Mishaehl'
- Lopes Sil'Vi
- Jugon Antuan
- Bondjuehll' Odreh
|
RU2551857C2 |
CATALYST SUITABLE FOR USE IN HYDROCONVERSION, CONTAINING AT LEAST ONE ZEOLITE AND METALS OF GROUPS VIII AND VIB, AND CATALYST OBTAINING |
2012 |
- Simon Loran
- Gishar Bertran
- Lapizardi Gregori
- Dyulo Yug
- De Grandi Valentina
- Minu Delfin
- Dat Zhan-Per
|
RU2621053C2 |
METHOD OF OBTAINING CATALYST USABLE IN HYDROPROCESSING AND IN HYDROCONVERSION |
2012 |
- Gishar Bertran
- Simon Loran
- Lopes Silvi
- De Grandi Valentina
- Minu Delfin
- Dat Zhan-Per
|
RU2627362C2 |
METHOD FOR HYDROTREATMENT OF VACUUM DISTILLATE USING SEQUENCE OF CATALYSTS |
2014 |
- Rua-Oberzhe Magali
- Gijon Emmanyuell
- Grezo Alin
|
RU2651269C2 |
CATALYST BASED ON FURAN COMPOUND AND ITS USE IN HYDROTREATMENT AND/OR HYDROCRACKING METHOD |
2018 |
- Carrette, Pierre-Louis
- Delcroix, Damien
|
RU2768503C2 |
METHOD OF REJUVENATING SPENT AND REGENERATED CATALYST FROM GASOLINE HYDRODESULPHURISATION PROCESS |
2019 |
- Devers, Elodie
- Girard, Etienne
- Leflaive, Philibert
|
RU2825326C2 |
CATALYST BASED ON γ-KETOVALERIC ACID AND USE THEREOF IN HYDROTREATMENT AND/OR HYDROCRACKING |
2016 |
|
RU2698326C2 |
CATALYST BASED ON γ-VALEROLACTONE AND/OR HYDROLYSIS PRODUCTS THEREOF AND USE THEREOF DURING HYDROPROCESSING AND/OR HYDROCRACKING METHOD |
2016 |
|
RU2705382C2 |
METHOD FOR PRODUCTION OF HYDROCONVERSION CATALYST, COMPRISING AT LEAST ONE NU-86 ZEOLITE |
2012 |
- Bondyuell Odre
- Gijon Emmanyuell
- Rua-Oberzhe Magali
|
RU2617987C2 |
TUNGSTEN-BASED VACANCY-KEGGIN-TYPE HETEROPOLYANION FOR HYDROCRACKING |
2009 |
- Bondjuehll' Odreh
- Bertonsini Fabris
- Ben Tejeb Karima
- Lamon'E Karol'
- Furn'E Mishel'
- Pejen Ehdmon
|
RU2509729C2 |